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The semi-analytical prediction of pollutants emissions from gas turbines in the conceptual design phase is addressed in this paper. The necessity of this work arose from an urgent need for a comprehensive model that can quickly provide data in the conceptual design phase. Based on the available inputs data in the initial phases of the design process, a chemical reactor network (CRN) is defined to model the combustion with a detailed chemistry. In this way, three different chemical mechanisms are studied for Jet-A aviation fuel. Furthermore, the droplet evaporation for liquid fuel and the non-uniformity in fuel-air mixture are modelled. The results of a developed augmented modelling tool are compared with the pollutants data of two annular engine's combustors. The CRN results have good agreement with the actual engine test rig emissions output. In conclusion, the augmented CRN has shown to be efficient in predicting engine emissions with a very short executing time (few seconds) using a small CPU requirement such as a personal computer.

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Purpose The purpose of this paper is to review the applications of the chemical reactor network (CRN) approach for modeling the combustion in gas turbine combustors and classify the CRN construction methods that have been frequently used by researchers. Design/methodology/approach This paper initiates with introducing the CRN approach as a practical tool for precisely predicting the species concentrations in the combustion process with lower computational costs. The structure of the CRN and its elements as the ideal reactors are reviewed in recent studies. Flow field modeling has been identified as the most important input for constructing the CRNs; thus, the flow field modeling methods have been extensively reviewed in previous studies. Network approach, component modeling approach and computational fluid dynamics (CFD), as the main flow field modeling methods, are investigated with a focus on the CRN applications. Then, the CRN construction approaches are reviewed and categorized based on extracting the flow field required data. Finally, the most used kinetics and CRN solvers are reviewed and reported in this paper. Findings It is concluded that the CRN approach can be a useful tool in the entire process of combustion chamber design. One-dimensional and quasi-dimensional methods of flow field modeling are used in the construction of the simple CRNs without detailed geometry data. This approach requires fewer requirements and is used in the initial combustor designing process. In recent years, using the CFD approach in the construction of CRNs has been increased. The flow field results of the CFD codes processed to create the homogeneous regions based on construction criteria. Over the past years, several practical algorithms have been proposed to automatically extract reactor networks from CFD results. These algorithms have been developed to identify homogeneous regions with a high resolution based on the splitting criteria. Originality/value This paper reviews the various flow modeling methods used in the construction of the CRNs, along with an overview of the studies carried out in this field. Also, the usual approaches for creating a CRN and the most significant achievements in this field are addressed in detail.

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