The theoretical maximum tensile strain--that is, elongation--of a single-walled carbon nanotube is almost 20%, but in practice only 6% is achieved. Here we show that, at high temperatures, individual single-walled carbon nanotubes can undergo superplastic deformation, becoming nearly 280% longer and 15 times narrower before breaking. This superplastic deformation is the result of the nucleation and motion of kinks in the structure, and could prove useful in helping to strengthen and toughen ceramics and other nanocomposites at high temperatures.
The kagome lattice of transition metal atoms provides an exciting platform to study electronic correlations in the presence of geometric frustration and nontrivial band topology, which continues to bear surprises. In this work, using spectroscopic imaging scanning tunneling microscopy, we discover a cascade of different symmetry-broken electronic states as a function of temperature in a new kagome superconductor, CsV3Sb5. At a temperature far above the superconducting transition Tc ~ 2.5 K, we reveal a tri-directional charge order with a 2a0 period that breaks the translation symmetry of the lattice. As the system is cooled down towards Tc, we observe a prominent V-shape spectral gap opening at the Fermi level and an additional breaking of the six-fold rotation symmetry, which persists through the superconducting transition. This rotation symmetry breaking is observed as the emergence of an additional 4a0 unidirectional charge order and strongly anisotropic scattering in differential conductance maps. The latter can be directly attributed to the orbital-selective renormalization of the V kagome bands. Our experiments reveal a complex landscape of electronic states that can co-exist on a kagome lattice, and provide intriguing parallels to high-Tc superconductors and twisted bilayer graphene.Quantum solids composed of atoms arranged on a lattice of corner-sharing triangles (kagome lattice) are a fascinating playground for the exploration of novel correlated and topological electronic phenomena [1][2][3][4] . Due to their intrinsic geometric frustration, kagome systems are predicted to host to a slew of exotic electronic states [5][6][7][8][9][10][11][12][13][14][15][16][17][18] , such as bond and charge ordering 7,8,10,[16][17][18] , spin liquid phases 5,15 and chiral superconductivity 9,10,17 . The majority of the experimental efforts thus far have focused on transition-metal kagome magnets, for example Co3Sn2S2 [19][20][21][22][23] FeSn 24,25 and Fe3Sn2 26,27 , in which different forms of magnetism dominate the low-temperature electronic ground state. Electronic correlations in the absence of magnetic ordering could in principle favor the emergence of new symmetry-broken electronic states, but this has been difficult to explore in many of the existing kagome materials due to a tendency towards magnetic ordering.
We report the temperature evolution of the detailed electronic band structure in FeSe singlecrystals measured by angle-resolved photoemission spectroscopy (ARPES), including the degeneracy removal of the dxz and dyz orbitals at the Γ/Z and M points, and the orbital-selective hybridization between the dxy and d xz/yz orbitals. The temperature dependences of the splittings at the Γ/Z and M points are different, indicating that they are controlled by different order parameters. The splitting at the M point is closely related to the structural transition and is attributed to orbital ordering defined on Fe-Fe bonds with a d-wave form in the reciprocal space that breaks the rotational symmetry. In contrast, the band splitting at the Γ/Z points remains at temperature far above the structural transition. Although the origin of this latter splitting remains unclear, our experimental results exclude the previously proposed ferro-orbital ordering scenario.
Abstract:A robust zero-energy bound state (ZBS) in a superconductor, such as a Majorana or Andreev bound state, is often a consequence of non-trivial topological or symmetry related properties, and can provide indispensable information about the superconducting state. Here we use scanning tunneling microscopy/spectroscopy to demonstrate, on the atomic scale, that an isotropic ZBS emerges at the randomly distributed interstitial excess Fe sites in the superconducting Fe(Te,Se). This ZBS is localized with a short decay length of ~ 10 Å, and surprisingly robust against a magnetic field up to 8 Tesla, as well as perturbations by neighboring impurities. We find no natural explanation for the observation of such a robust zero-energy bound state, indicating a novel mechanism of impurities or an exotic pairing symmetry of the iron-based superconductivity.Main Text: Superconductivity arises from the macroscopic quantum condensation of electron pairs. The symmetry of the wave-function of these pairs is one of the most essential aspects of the microscopic pairing mechanism. Since the impurity-induced local density of states (DOS) is sensitive to the pairing symmetry, it can be used to test the symmetry of the order parameter and to probe the microscopic pairing mechanism. Being a local probe with atomic resolution, scanning tunneling microscopy/spectroscopy (STM/S) (1) has played a key role in this respect, especially in the study of high-TC cuprate superconductors (2,3).Since its discovery, new compounds of iron-based superconductor (IBSC) continue to be found. However, the pairing symmetry remains a central unresolved issue. So far,
We report muon spin rotation (μSR) experiments together with first-principles calculations on microscopic properties of superconductivity in the kagome superconductor LaRu 3 Si 2 with T c 7K. Below T c , μSR reveals type-II superconductivity with a single s-wave gap, which is robust against hydrostatic pressure up to 2 GPa. We find that the calculated normal state band structure features a kagome flat band, and Dirac as well as van Hove points formed by the Ru-dz 2 orbitals near the Fermi level. We also find that electron-phonon coupling alone can only reproduce a small fraction of T c from calculations, which suggests other factors in enhancing T c such as the correlation effect from the kagome flat band, the van Hove point on the kagome lattice, and the high density of states from narrow kagome bands. Our experiments and calculations taken together point to nodeless moderate coupling kagome superconductivity in LaRu 3 Si 2 .
The cuprate superconductors distinguish themselves from the conventional superconductors in that a small variation in the carrier doping can significantly change the superconducting transition temperature ( ), giving rise to a superconducting dome where a pseudogap 1,2 emerges in the underdoped region and a Fermi liquid appears in the overdoped region. Thus a systematic study of the properties over a wide doping range is critical for understanding the superconducting mechanism. Here, we report a new technique to continuously dope the surface of Bi 2 Sr 2 CaCu 2 O 8+x through an ozone/vacuum annealing method. Using in-situ ARPES, we obtain precise quantities of energy gaps and the coherent spectral weight over a wide range of doping. We discover that the d-wave component of the quasiparticle gap is linearly proportional to the Nernst temperature that is the onset of superconducting vortices 3 , strongly suggesting that the emergence of superconducting pairing is concomitant with the onset of free vortices, with direct implications for the onset of superconducting phase coherence at and the nature of the pseudogap phenomena.Bi 2 Sr 2 CaCu 2 O 8+x (Bi2212) single crystals have been extensively studied by angle-resolved photoemission spectroscopy (ARPES) and scanning tunneling spectroscopy (STS) 4,5 , two of the major experimental techniques for probing the cuprates. However, high-quality Bi2212 crystals can be only obtained within a narrow doping range. Moreover, surface cleaving, necessary for surface techniques such as ARPES and STS, posses a serious problem for quantitative comparisons from sample to sample due to variation of surface conditions. Realizing that the doping level in this material is solely controlled by the excess oxygen concentration, we use ozone/vacuum annealing to continuously change the doping level of the surface layers, which are subsequently measured by in-situ ARPES (Figs. 1a-c).
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