On the basis of reiterating the concept of grain boundary engineering (GBE), the recent progress in the theoretical models and mechanisms of twin-related GBE optimization and its effect on the mechanical properties is systematically summarized in this review. First, several important GBE-quantifying parameters are introduced, e.g., the fraction of special grain boundaries (GBs), the distribution of triple-junctions, and the ratio of twin-related domain size to grain size. Subsequently, some theoretical models for the GBE optimization in face-centered cubic (FCC) metals are sketched, with a focus on the model of “twin cluster growth” by summarizing the in-situ and quasi-in-situ observations on the evolution of grain boundary character distribution during the thermal-mechanical process. Finally, some case studies are presented on the applications of twin-related GBE in improving the various mechanical properties of FCC metals, involving room-temperature tensile ductility, high-temperature strength-ductility match, creep resistance, and fatigue properties. It has been well recognized that the mechanical properties of FCC materials could be obviously improved by a GBE treatment, especially at high temperatures or under high cyclic loads; under these circumstances, the materials are prone to intergranular cracking. In short, GBE has tremendous potential for improving the mechanical properties of FCC metallic materials, and it is a feasible method for designing high-performance metallic materials.
The critical roles of short-range ordering (SRO) in the grain boundary character distribution (GBCD) optimization of Ni-Cr alloys with high stacking fault energies were experimentally studied by thermomechanical treatments. It is found that, with the enhancement of the SRO degree (or the increase in Cr content), the dislocation slip mode changes from wavy slip to planar slip, and even deformation twins (DTs) appear in the cold-rolled Ni-40at.%Cr alloy. Within the lower level of Cr content (≤20 at.%), the optimized result of GBCD is conspicuous with the increase in Cr content. As the Cr content is higher than 20 at.%, the GBCD optimization of Ni-Cr alloys cannot be further enhanced, since the cold rolling induced DTs would hinder the growth of twin related domains during subsequent annealing.
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