Colloidal migration in a temperature gradient is referred to as thermophoresis. In contrast to particles with a spherical shape, we show that elongated colloids may have a thermophoretic response that varies with the colloid orientation. Remarkably, this can translate into a non-vanishing thermophoretic force in the direction perpendicular to the temperature gradient. Opposite to the friction force, the thermophoretic force of a rod oriented with the temperature gradient can be larger or smaller than when oriented perpendicular to it. The precise anisotropic thermophoretic behavior clearly depends on the colloidal rod aspect ratio, and also on its surface details, which provides an interesting tunability to the devices constructed based on this principle. By means of mesoscale hydrodynamic simulations, we characterize this effect for different types of rod-like colloids.
Fluid flow along microchannels can be induced by keeping opposite walls at different temperatures, and placing elongated tilted pillars inside the channel. The driving force for this fluid motion arises from the anisotropic thermophoretic effect of the elongated pillars that generates a force parallel to the walls, and perpendicular to the temperature gradient. The force is not determined by the thermophilic or thermophobic character of the obstacle surface, but by the geometry and the thermophoretic anisotropy of the obstacle. Via mesoscale hydrodynamic simulations, we investigate the pumping properties of the device as a function of the channel geometry, and pillar surface properties. Applications as fluidic mixers, and fluid alternators are also outlined, together with the potential use of all these devices to harvest waste heat energy. Furthermore, similar devices can be also built employing diffusiophoresis or electrophoresis. arXiv:1808.05028v2 [cond-mat.soft]
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