Using tung oil as the raw material, a new bio-based prepolymer was synthesized by reacting with ARA/HEA as the matrix and then reacting with the diluent and photoinitiator to synthesize a new bio-based prepolymer-acrylate-epoxy tung oil polypolymer.

Tung oil is an important dry grease. In order to overcome the deficiencies of traditional processes in oil production, the preparation of tung oil was carried out by the butane-subcritical method. A response surface optimization experiment was carried out based on Design-Expert software, and the best process parameters were obtained. The extraction temperature was 42.98 °C, the extraction time was 43.77 min, the particle size of the raw material was 38.88 mesh, and the oil yield of tung oil under this condition reached 67.437%. The fatty acid composition of tung oil was analyzed by Gas Chromatography-Mass Spectrometry (GC-MS): the content of α-oleostearic acid was 74.99%, linoleic acid content was 8.83%, oleic acid content was 7.42%, palmitic acid content was 2.02%, and stearic acid content was 4.35%. Through the analysis of the oil sample obtained, five indicators showed that the process of obtaining oil products met the requirements of the national standard. By simulating the subcritical n-butane/tung oil dissolution equilibrium model, the miscible dynamic equilibrium of tung oil in subcritical n-butane was studied at temperatures in the range of 35–50 °C and an equilibrium time of 40 min, and the kinetic equations of oil extraction at different temperatures were obtained, with a coefficient of determination (R2) greater than 0.99. The oil extraction rate was up to 67.12 ± 0.05% under optimal extraction conditions through the optimization of univariate and response surface experimental design. Using 1stOpt data processing software, the data of tung oil extraction rate at different times were fitted, and it was found that the Patricelli model accurately elucidated the kinetic process of tung oil extraction through subcritical n-butane, with R2 greater than 0.99.

Tung oil (TO)/ultraviolet (UV) photo-composite curing material possesses the characteristics of low curing temperature, low material shrinkage and low environmental pollution. Accordingly, this material must be developed and utilized with the conjugated double bonds contained in the long chain of the main structure (α-tung acid) molecules in the refined TO. The aforementioned material can be chemically modified using a variety of chemical methods to develop a new TO-based UV photocurable material due to its unique chemical properties. This work reviews the research progress of TO/UV photo-composite curing materials in recent years. Firstly, the chemical structure and application of TO and UV Photocatalysis Technology were briefly introduced. Secondly, the research status of novel TO/UV photo-composite curing materials developed by the Diels-Alder reaction was discussed. The method and curing effect of the UV curing system constructed by other chemically modified TO were also discussed. Thereafter, the application of TO in industrial production is introduced from four directions: the application of TO in biodiesel, the application in synthetic resin, the application in self-healing coating and microcapsules and other applications. Finally, the research and application prospects of TO/UV photo-composite curing materials were presented.