When a water drop is placed onto a soft polymer network, a wetting ridge develops at the drop periphery. The height of this wetting ridge is typically governed by the drop surface tension balanced by elastic restoring forces of the polymer network. However, the situation is more complex when the network is swollen with fluid, because the fluid may separate from the network at the contact line. Here we study the fluid separation and network deformation at the contact line of a soft polydimethylsiloxane (PDMS) network, swollen with silicone oil. By controlling both the degrees of crosslinking and swelling, we find that more fluid separates from the network with increasing swelling. Above a certain swelling, network deformation decreases while fluid separation increases, demonstrating synergy between network deformation and fluid separation. When the PDMS network is swollen with a fluid having a negative spreading parameter, such as hexadecane, no fluid separation is observed. A simple balance of interfacial, elastic, and mixing energies can describe this fluid separation behavior. Our results reveal that a swelling fluid, commonly found in soft networks, plays a critical role in a wetting ridge.
Perovskite solar cells (PSCs) consisting of interfacial two- and three-dimensional heterostructures that incorporate ammonium ligand intercalation have enabled rapid progress toward the goal of uniting performance with stability. However, as the field continues to seek ever-higher durability, additional tools that avoid progressive ligand intercalation are needed to minimize degradation at high temperatures. We used ammonium ligands that are nonreactive with the bulk of perovskites and investigated a library that varies ligand molecular structure systematically. We found that fluorinated aniliniums offer interfacial passivation and simultaneously minimize reactivity with perovskites. Using this approach, we report a certified quasi–steady-state power-conversion efficiency of 24.09% for inverted-structure PSCs. In an encapsulated device operating at 85°C and 50% relative humidity, we document a 1560-hour T 85 at maximum power point under 1-sun illumination.
Soft, slippery surfaces have gained increasing attention because of their wide range of potential applications, for example in biomaterials, self-cleaning, antifouling, liquid collection, and more. One approach to prepare a soft, slippery surface is by swelling a cross-linked polymer network with a lubricant. However, an understanding of how swelling and cross-linking relate to slippery properties is still underdeveloped for low modulus elastomers. We study when a water drop sticks or slides on a vertical, silicone oil-swollen polydimethylsiloxane (PDMS) elastomer as a function of the degree of crosslinking and the degree of swelling. Our results indicate that the critical water drop volume required for sliding is strongly controlled by the degree of swelling; higher swelling leads to lower critical drop volumes. In addition, we demonstrate that highly swollen surfaces, and not lightly swollen surfaces, recover their slippery behavior during an aging process after they are rinsed with water. This is likely associated with regeneration of an oil-layer on the surface coming from the bulk substrate, illustrating the durability of lubricantswollen elastomers for practical uses.
Two-part, commercial silicone elastomers are used in a variety of fundamental soft materials research and industrial applications due to their wide availability, ease of use, low cost, and mechanical tunability. This work seeks to create a library of moduli for three common elastomer systems with varied mixing ratios: Sylgard 184, Solaris, and Ecoflex 00-30, as well as provide a comparison of their adhesive properties. Shear storage moduli are quantified using parallel plate oscillatory shear rheology. The work of debonding is measured with spherical probe adhesion testing, and the static, advancing, and receding contact angles are measured via goniometer. Sylgard 184 can have shear moduli ranging from $0.5 kPa-620 kPa, Solaris from $0.6 kPa-175 kPa, and EF from $1.3 kPa-35 kPa measured at a frequency of 0.01 rad/s. In general, increasing mixing ratios creates softer samples. Additionally, softer samples are universally more adhesive, regardless of the material system. When comparing the different material systems, Sylgard 184 is generally the most adhesive, followed closely by Solaris, and then by Ecoflex 00-30. Our study offers a baseline dataset of modulus values and comparative adhesion to help researchers determine an appropriate commercial silicone for their application.
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