devices to allow energy release at night and for continuous supply under low wind conditions. The most prevalent type of secondary energy storage uses lithiumion batteries (LIBs), that possess high energy density and long cycle life and have brought about a remarkable technical revolution for portable electronics, vehicles, and many other aspects in daily life. [1] However, considering the growing cost of the limited lithium resources and safety concerns derived from intrinsic chemical activity of metallic lithium and its combustible ester electrolytes, aqueous rechargeable batteries have been recently spotlighted as promising alternatives especially for utilization of large-scale energy storage stations. [2] Among them, aqueous zinc-ion batteries (AZIBs) have gained exceptional interest in aqueous systems due to the beneficial physicochemical properties of zinc, that is, i) a high theoretical volumetric capacity around 5585 mAh cm −3 of a metallic zinc anode compared with 2061 mAh cm −3 and 1129 mAh cm −3 for lithium and sodium anodes, respectively; ii) low redox potential of −0.762 V versus standard hydrogen electrode, and iii) electrochemical stability of metallic zinc in its sulfate solutions at near neutral or slightly acidic aqueous electrolyte providing the batteries with safe, costeffective, and environment-friendly characteristics. [3][4][5][6] Cost-effective and environmentally-friendly aqueous zinc-ion batteries (AZIBs) exhibit tremendous potential for application in grid-scale energy storage systems but are limited by suitable cathode materials. Hydrated vanadium bronzes have gained significant attention for AZIBs and can be produced with a range of different pre-intercalated ions, allowing their properties to be optimized. However, gaining a detailed understanding of the energy storage mechanisms within these cathode materials remains a great challenge due to their complex crystallographic frameworks, limiting rational design from the perspective of enhanced Zn 2+ diffusion over multiple length scales. Herein, a new class of hydrated porous δ-Ni 0.25 V 2 O 5 .nH 2 O nanoribbons for use as an AZIB cathode is reported. The cathode delivers reversibility showing 402 mAh g −1 at 0.2 A g −1 and a capacity retention of 98% over 1200 cycles at 5 A g −1 . A detailed investigation using experimental and computational approaches reveal that the host "δ" vanadate lattice has favorable Zn 2+ diffusion properties, arising from the atomic-level structure of the well-defined lattice channels. Furthermore, the microstructure of the as-prepared cathodes is examined using multi-length scale X-ray computed tomography for the first time in AZIBs and the effective diffusion coefficient is obtained by imagebased modeling, illustrating favorable porosity and satisfactory tortuosity.
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
Batteries that extend performance beyond the intrinsic limits of Li-ion batteries are among the most important developments required to continue the revolution promised by electrochemical devices. Of these next-generation batteries, lithium sulfur (Li–S) chemistry is among the most commercially mature, with cells offering a substantial increase in gravimetric energy density, reduced costs and improved safety prospects. However, there remain outstanding issues to advance the commercial prospects of the technology and benefit from the economies of scale felt by Li-ion cells, including improving both the rate performance and longevity of cells. To address these challenges, the Faraday Institution, the UK’s independent institute for electrochemical energy storage science and technology, launched the Lithium Sulfur Technology Accelerator (LiSTAR) programme in October 2019. This Roadmap, authored by researchers and partners of the LiSTAR programme, is intended to highlight the outstanding issues that must be addressed and provide an insight into the pathways towards solving them adopted by the LiSTAR consortium. In compiling this Roadmap we hope to aid the development of the wider Li–S research community, providing a guide for academia, industry, government and funding agencies in this important and rapidly developing research space.
Defect-engineered vanadium bronzes with ultra-fast zinc-ion diffusion kinetics and excellent stability were created by a two-pronged strategy as cathode materials in aqueous zinc-ion batteries.
Low-temperature etching of ZIF-67 is proposed for ultra-small cobalt/cobalt-oxide nanoparticles in nitrogen-doped graphene-networks as an efficient electrocatalyst for the oxygen reduction reaction.
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