Reduced graphene oxides (rGO) are synthesized via reduction of GO with reducing agents as a hole‐extraction layer for high‐performance inverted planar heterojunction perovskite solar cells. The best efficiencies of power conversion (PCE) of these rGO cells exceed 16%, much greater than those made of GO and poly(3,4‐ethenedioxythiophene):poly(styrenesulfonate) films. A flexible rGO device shows PCE 13.8% and maintains 70% of its initial performance over 150 bending cycles. It is found that the hole‐extraction period is much smaller for the GO/methylammonium lead‐iodide perovskite (PSK) film than for the other rGO/PSK films, which contradicts their device performances. Photoluminescence and transient photoelectric decays are measured and control experiments are performed to prove that the reduction of the oxygen‐containing groups in GO significantly decreases the ability of hole extraction from PSK to rGO and also retards the charge recombination at the rGO/PSK interface. When the hole injection from PSK to GO occurs rapidly, hole propagation from GO to the indium‐doped tin oxide (ITO) substrate becomes a bottleneck to overcome, which leads to a rapid charge recombination that decreases the performance of the GO device relative to the rGO device.
Reducing collisions in UHF RFID systems is a crucial problem. In most anti-collision designs, the reader has to estimate the number of tags within its reading range during the interrogation process. Most of the approaches estimate the number of tags with observations in multiple time slots. Since estimation error varies along with the initial frame length and the number of tags, system efficiency is affected by both of them. To reduce the sensitiveness to them and improve system efficiency, we propose a novel MAC-PHY crosslayer anti-collision algorithm based on Bayesian inference. Specifically, each frame is allowed to end at an early stage and a slot-by-slot estimator is proposed. Benefit from its slot-by-slot nature, system efficiency is more stable and independent on the initial frame length and very close to the upper bound of dynamic framed slotted ALOHA (DFSA) algorithm. The performance of the proposed method is compared with the stateof-the-art algorithms through numeric simulations. The results show that the proposed solution significantly outperforms the compared ones. INDEX TERMS Anti-collision, Bayesian estimate, cross-layer, UHF RFID.
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