We demonstrate strong magnon-photon coupling of a thin-film permalloy device fabricated on a coplanar superconducting resonator. A coupling strength of 0.152 GHz and a cooperativity of 68 are found for a 30-nm-thick permalloy stripe. The coupling strength is tunable by rotating the biasing magnetic field or changing the volume of permalloy. We also observe an enhancement of magnonphoton coupling in the nonlinear regime of the superconducting resonator, which is mediated by the nucleation of dynamic flux vortices. Our results demonstrate a critical step towards future integrated hybrid systems for quantum magnonics and on-chip coherent information transfer.

BackgroundRadiomics is an emerging field in oncological research. In this study, we aimed at developing a radiomics score (rad-score) to estimate postoperative recurrence and survival in patients with solitary hepatocellular carcinoma (HCC).MethodsA total of 319 solitary HCC patients (training cohort: n = 212; validation cohort: n = 107) were enrolled. Radiomics features were extracted from the artery phase of preoperatively acquired computed tomography (CT) in all patients. A rad-score was generated by using the least absolute shrinkage and selection operator (lasso) logistic model. Kaplan-Meier and Cox’s hazard regression analyses were used to evaluate the prognostic significance of the rad-score. Final nomograms predicting recurrence and survival of solitary HCC patients were established based on the rad-score and clinicopathological factors. C-index and calibration statistics were used to assess the performance of nomograms.ResultsSix potential radiomics features were selected out of 110 texture features to formulate the rad-score. Low rad-score positively correlated with aggressive tumor phenotypes, like larger tumor size and vascular invasion. Meanwhile, low rad-score was significantly associated with increased recurrence and reduced survival. In addition, multivariate analysis identified the rad-score as an independent prognostic factor (recurrence: Hazard ratio (HR): 2.472, 95% confident interval (CI): 1.339–4.564, p = 0.004;survival: HR: 1.558, 95%CI: 1.022–2.375, p = 0.039). Notably, the nomogram integrating rad-score had a better prognostic performance as compared with traditional staging systems. These results were further confirmed in the validation cohort.ConclusionsThe preoperative CT image based rad-score was an independent prognostic factor for the postoperative outcome of solitary HCC patients. This score may be complementary to the current staging system and help to stratify individualized treatments for solitary HCC patients.Electronic supplementary materialThe online version of this article (10.1186/s12885-018-5024-z) contains supplementary material, which is available to authorized users.

We experimentally identify coherent spin pumping in the magnon-magnon hybrid modes of permalloy/yttrium iron garnet (Py/YIG) bilayers. Using broadband ferromagnetic resonance, an "avoided crossing" is observed between the uniform mode of Py and the spin wave mode of YIG due to the fieldlike interfacial exchange coupling. We also identify additional linewidth suppression and enhancement for the in-phase and out-of-phase hybrid modes, respectively, which can be interpreted as concerted dampinglike torque from spin pumping. Our analysis predicts inverse proportionality of both fieldlike and dampinglike torques to the square root of the Py thickness, which quantitatively agrees with experiments.Coherent information processing has recently become an emerging topic for the post-CMOS electronics era [1,2]. In spintronics, exchange-induced magnetic excitations, called spin waves, or magnons [3,4], are good candidates because information can be encoded by both the amplitude and the phase of spin waves. For example, the interference of coherent spin waves can be engineered for spin wave logic operations [5][6][7]; the coherent interaction of spin-torque oscillators leads to mutual synchronization [8][9][10][11][12][13], which can be applied in artificial neural networks [14,15]; and the coherent coupling between magnons and microwave cavities [16][17][18][19][20][21][22] opens up new opportunities for magnon-based quantum information science [23,24].Recently, strong coupling between two magnonic systems has been observed [25][26][27], which allows excitations of forbidden spin wave modes and high group velocity of propagating spin waves [28,29]. The coupling is dominated by the exchange interaction at the interface of the magnetic bilayers, providing a new pathway to coherently transfer magnon excitations between two magnetic systems possessing distinctive properties: from conductor to insulator, from uniform to nonuniform mode and from high-damping to low-damping systems. However, the underlying physical mechanisms of the coupling are still not fully understood. First, what are the key parameters that dictate the coupling efficiency and enable one to reach the strong-coupling regime? Second, with the interfacial exchange coupling acting as a fieldlike torque, is there a dampinglike torque associated with spin pumping [30][31][32][33]? The second question is particularly important for optimizing the coherence of spin wave transfer in hybrid systems. Furthermore, any parasitic effect on the incoherent spin current from the conduction band is well-removed [34-36] by using magnetic insulators such as yttrium iron garnet (Y 3 Fe 5 O 12 , YIG) [29,37,38], which facilitates the study of spin pumping coherency.In this work, we study YIG/permalloy (Ni 80 Fe 20 , Py) bilayers with varying Py thicknesses. By using a much thinner YIG film compared with previous work [25,27], we define well-separated perpendicular standing spin wave (PSSW) modes in YIG and create an avoided crossing much larger than the linewidths, allowing us to stud...

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Hydrogels, exhibiting wide application prospects in soft robotics, tissue engineering, implantable electronics, etc., upon functioning often require to adhere to substrates especially in wet environments despite that most hydrogels are nonsticky because of their high water content and hydrophilicity. Herein, a strategy to rapidly reverse the adhesion properties of hydrogels via surface anchoring very thin adhesive coatings is reported. Inspired by mussel adhesion, poly(vinyl alcohol) hydrogel is first coated with polymerized tannic acid that chelates with Fe 3+ , which serves as the interface bonding layer. Subsequently, a wet adhesive poly(dopamine methacrylamide-co-methoxyethyl acrylate) is firmly anchored to form the very thin adhesive coating (<10 µm) that can generate high adhesion strength both in the air and underwater. The adhesive coating also endows hydrogels with high water retention capacity under warm condition (50 °C) and is able to get on-demand functionalization on the designated area to achieve asymmetric adhesion, static and dynamic control over wettability. The strategy demonstrates potentials for broad applications from biomedicine to wearable electronics.

The accumulation of ice in winter has brought many problems in industrial production and everyday life, and how to prevent icing or remove ice rapidly has aroused great attention from researchers in recent years. In this work, we demonstrated a strategy of using a superhydrophobic photothermal and thermal isolation macroporous xerogel (PMX) to delay icing and remove ice efficiently under faint sunlight irradiation. An oriented macroporous xerogel was prepared by an ice templating method, and multi-walled carbon nanotubes acting as the photothermal genesis component under sunlight irradiation were introduced into the xerogel. After fluorination, the PMX presented a robust water repellency and delayed icing. More importantly, numerous macropores in the PMX matrix acted as the thermal barrier that can restrict heat transmission to surroundings at maximum, which guarantees efficient anti-icing and de-icing in low temperature. Water on the PMX surface can never freeze at −30 °C under 0.25 kW/m2 (“0.25 sun”) sunlight irradiation. The outdoor experiment also has confirmed the availability of PMX in a natural winter environment. The PMX integrated with thermogenesis and thermo-isolation functions provides a new route for highly efficient anti-icing and de-icing.

Four novel N-heterocyclic carbene (NHC) silver complexes, , have been synthesized and characterized. The single X-ray crystal diffraction data indicate a dinuclear solid-state structure for and and a mononuclear structure for and . These complexes have been successfully used as efficient catalysts for the C-H activating carboxylation of terminal alkynes with CO2. A wide range of substrates with various functional groups afforded the corresponding aryl or alkyl substituted propiolic acids in good yields under mild conditions. Moreover, the role of bases and the reaction mechanism is thoroughly discussed.

The utilization of carbon dioxide as a feedstock for the production of raw chemicals is of high current industrial interest. One attractive reaction is the transformation of carbon dioxide into acrylic acid or acrylates. The cleavage of the Ni─O bond of nickelalactones may result in the formation of acrylates. In this work, C2H5I, CF3CH2I and CF3I are studied as alkylation reagents for the Ni─O ring opening of nickelalactones. The results indicate that both C2H5I and CF3CH2I are able to release acrylates from nickelalactones. Based on the experimental evidence and literature precedents, a mechanism – proceeding via Ni─O ring opening of nickelalactone, β‐H elimination to release the acrylate and reductive elimination for recovery of the Ni(0) species – is proposed.