As a representative intrinsic p-type inorganic semiconductor material, cuprous oxide (Cu 2 O) has been widely used in photovoltaics, catalysis, chemical industries, and other fields, owning an extremely important position. For a long time, the literature on the preparation methods and preparation technologies of Cu 2 O have been relatively scattered and independent, resulting in a certain degree of obstacles and difficulty in obtaining relevant technical knowledge and understanding the internal principles. Aiming at the progress and innovation of Cu 2 O preparation methods and technologies in recent years, combined with our team's long-term experience accumulation and research results, this article focuses on the classification, principles, and characteristics of the various Cu 2 O preparation methods and also involves representative applications and performance in the light energy utilization area. This review aims to provide reference and guidance for the preparation and research of Cu 2 O and other related inorganic oxide semiconductors.
Membrane distillation (MD) is a promising alternative approach for desalination, especially for highsalinity brines. Its application has been limited by its high operational cost because of the energy consumption required for hydraulic circulation and heating the entire circulating feed. Localized heating of the feed by Joule heating diminishes energy consumption, but the potential charging on the electrothermal material surface causes water splitting and membrane degradation in high-salinity environments. Herein, a novel reverse Joule-heating air gap MD method was designed in which an electrothermal material was placed at the air gap, isolating itself from saline water. Even though the Joule-heating layer was at the air gap side, 90.56% of heat flowed into the saline water for heating the feed. The opposite temperature gradient in the membrane matrix as opposed to conventional MD-mitigated membrane wetting was caused by capillary condensation. This novel electrothermal-driven MD configuration is worthy to be introduced into applications.
The mid-plane model for warpage simulation of injection-molded parts requires a mid-plane mesh whose transformation is considerably time consuming. To overcome this drawback, a surface model-based warpage simulation is presented, in which the part is represented as a perfect bonding of two half-thickness plates with their reference surfaces at the outer boundary of the part. The plates over the surface mesh are modeled as flat shell elements, and a new triangular flat shell element is developed which combines an Assumed Natural DEviatoric Strain (ANDES) based membrane component and a Refined Nonconforming Element Method (RNEM) based bending component. The bonding is accomplished by multipoint constraints and a Lagrange multiplier based elimination method is proposed for constraint application. The results show that compared with some popular shell elements, ANSYS, Moldflow and the experiments, the presented model exhibits a high performance in computation accuracy. POLYM. ENG. SCI., 51:785-794, 2011. ª 2011
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Cu/ZnO catalyst was prepared by co-precipitation method inside microchannel reactor and characterized by X-Ray diffraction (XRD), thermo gravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and high-resolution transmission electron microscopy (HRTEM). The XRD analysis of precursors demonstrates that, compared with the sample prepared by conventional batch reactor, more Zn 2+ are incorporated into malachite structure,which is attributed to the relatively uniform distribution of Cu, Zn elements in initial precipitates caused by the excellent mixing performance of the microchannel reactor. Higher decomposition temperature of carbonate species trapped in the interfaces between CuO and ZnO and higher binding energy of Cu2p 3/2 indicate that sample prepared by the new reactor possess a stronger interface interaction, which derives from the more intimate contact between oxide components. This supposition is confirmed by the HRTEM images and the stronger interface interaction in the final reduced catalyst can improve catalytic performance on methanol synthesis.
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