Abstract:The Tibetan Plateau has one of the most complex climates in the world. Analysis of the climate in this region is important for understanding the climate change worldwide. In this study, climate patterns and trends in the Tibetan Plateau were analysed for the period from 1961 to 2001. Air temperature and precipitation were analysed on monthly and annual time scales using data collected from the National Meteorological Centre, China Meteorological Administration. Nonlinear slopes were estimated and analysed to investigate the spatial and temporal trends of air temperature and precipitation in the Tibetan Plateau using a Mann-Kendall method. Spatial analysis of air temperature and precipitation variability across the Tibetan Plateau was undertaken. While most trends are local in nature, there are general basinwide patterns. Temperature during the last several decades showed a long-term warmer trend, especially the areas around Dingri and Zogong stations, which formed two increasing centres. Only one of the stations investigated exhibited decreasing trend, and this was not significant. Precipitation in the Tibetan Plateau has increased in most regions of the study area over the past several decades, especially in the eastern and central part, while the western Tibetan Region exhibited a decreased trend over the same period.

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The first enantioselective total synthesis of antifungal agent Sch 38516, also known as fluvirucin B1, is described. The synthesis includes a convergent asymmetric preparation of amine 17 and acid 18, which are then united to afford diene 62. Metal-catalyzed transformations play a crucial role in the synthesis of the latter moiety. Of particular note are the diastereo- and enantioselective Zr-catalyzed alkylations, a tandem Ti- and Ni-catalyzed process that constitutes a hydrovinylation reaction, and a Ru-catalyzed alcohol oxidation to afford carboxylic acid 18. The requisite carbohydrate 38 is synthesized in a highly diastereo- and enantioselective fashion. Optical purity of the carbohydrate moiety arises from the use of the asymmetric dihydroxylation method of Sharpless; diastereochemical control is achieved through a selective dipolar [3 + 2] cycloaddition with a readily available amine serving as the chiral auxiliary. Union of the appropriately outfitted carbohydrate 71 and diene 62 through an efficient and diastereoselective glycosylation is followed by a remarkably efficient Mo-catalyzed macrocyclization that proceeds readily at room temperature.

Abstract:Some previous studies have shown that drying-up of the lower Yellow River resulted from decreasing precipitation and excessive industrial and agricultural consumption of water from the middle and downstream regions of the Yellow River. On the basis of average air temperature, precipitation, and pan evaporation data from nearly 80 gauging stations in the Yellow River basin, the monotonic trends of major climate variables over the past several decades are analysed. The analysis was mainly made for 12 months and the annual means. The isograms for annual and typical months are given in the paper. The result shows that the average temperature in the study area exhibits an increasing trend, mainly because of the increase of temperature in December, January and February. The largest trend is shown in December and the smallest is in August. There are 65 of 77 stations exhibiting a downward trend for annual precipitation. In all seasons except summer, there is a similar trend in the upstream region of the Yellow River, south of latitude 35°N. It is interesting to note that the pan evaporation has decreased in most areas of the Yellow River basin during the past several decades. April and July showed the greatest magnitude of slope, and the area from Sanmenxia to Huayuankou as well as the Yiluo River basin exhibited the strongest declining trend. The conclusion is that the decreasing pan evaporation results from complex changes of air temperature, relative humidity, solar radiation, and wind speed, and both climate change and human activities have affected the flow regime of the Yellow River during the past several decades.

This article provides a review of scientific articles addressing the topic of knowledge hiding in organizations. Based on a descriptive analysis, bibliometric analysis, and content analysis of a sample of 81 articles published in the academic journals in the Web of Science from 2012 to 2020, we identify the main areas and current dynamics of knowledge hiding research. Our results show that the central research themes of knowledge hiding include five clusters: concept and dimensions, antecedents, consequences, theories, and influence mechanisms. Based on our findings, we suggest future research should further develop the concept and dimensions of knowledge hiding; probe deeper into the consequences of knowledge hiding; explore multilateral, cross-level, and collective knowledge hiding; employ innovative theoretical perspectives and research methods to study knowledge hiding; and address how cultural and other contextual factors may shape the knowledge hiding behavior.