A flexible and robust MoS2-graphene hybrid paper with an excellent lithium storage capacity is fabricated through cross-linking by a polymer ligand, PEO, and shows potential for the development of high-performance film anodes.
We report a universal strategy for the hierarchical assembly of nanoparticles on various 2D materials, resulting in functional 0/2D nanohybrids holding great promise in catalysis, energy storage, and chemical and biological sensing.
h-BN, as an isoelectronic analogue of graphene, has improved thermal mechanical properties. Moreover, the liquid-phase production of h-BN is greener since harmful oxidants/reductants are unnecessary. Here we report a novel hybrid architecture by employing h-BN nanosheets as 2D substrates to load 0D Fe3O4 nanoparticles, followed by phenol/formol carbonization to form a carbon coating. The resulting carbon-encapsulated h-BN@Fe3O4 hybrid architecture exhibits synergistic interactions: 1) The h-BN nanosheets act as flexible 2D substrates to accommodate the volume change of the Fe3O4 nanoparticles; 2) The Fe3O4 nanoparticles serve as active materials to contribute to a high specific capacity; and 3) The carbon coating not only protects the hybrid architecture from deformation but also keeps the whole electrode highly conductive. The synergistic interactions translate into significantly enhanced electrochemical performances, laying a basis for the development of superior hybrid anode materials.
Two-dimensional (2D) nanocomposites as lubricant additives have been widely studied, but the synthetic process of the nanocomposites is not always environmentally friendly or economical. In this study, a new 2D nanocomposite, Fe 3 O 4 /h-BN, has been prepared by physical mixing of exfoliated h-BN nanosheets and organically modified Fe 3 O 4 nanoparticles. The nanocomposite displays a unique 2Dlayered structure without folds or wrinkles. The Fe 3 O 4 nanoparticles are uniformly dispersed on the h-BN nanosheet surfaces with the help of an elegant self-assembly strategy from van der Waals interactions. For the first time, Fe 3 O 4 /h-BN is studied as a lubricant additive and it exhibits excellent tribological properties. The coefficient of friction (COF) and the wear depth can be respectively reduced by 47% and 80% compared with the base oil. Based on the advantages of a simple and low-cost synthetic process and significant tribological properties, Fe 3 O 4 /h-BN offers great potential for lubrication application.
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