NSFC [20873113, 20833005, 20933004]; MOST [2007DFA40890]; Research Fund [200803841035]; Fujian Provincial Department of Science and Technology [2008F3099, 200810025
Electrochemical shape-controlled synthesis of metal nanocrystal (NC) catalysts bounded by high-index facets with high surface energy was achieved by developing a square-wave potential route. Tetrahexahedral Pt NCs with 24 {hk0} facets, concave hexoctahedral Pt NCs with 48 {hkl} facets, and multiple twinned Pt nanorods with {hk0} facets were produced. The method was employed also to synthesize successfully trapezohedral Pd NCs with 24 {hkk} facets, and concave hexoctahedral Pd NCs with 48 {hkl} facets. It has been tested that, thanks to the high-index facets with high density of atomic steps and dangling bonds, the tetrahexahedral Pt NCs exhibit much enhanced catalytic activity for equivalent Pt surface areas for electrooxidation of small organic fuels such as ethanol. These results demonstrate that the developed square-wave potential method has surmounted the limit of conventional chemical methods that could synthesize merely metal nanocrystals with low surface energy, and opened a new prospect avenue in shape-controlled synthesis of nanoparticle catalysts with high surface energy and enhanced activity.
Facettenreich: Platin‐Nanokristalle auf Industrieruß wurden elektrochemisch synthetisiert (HIF‐Pt/C, siehe Bild). Die Nanokristalle sind durch hoch indizierte Facetten und eine hohe Dichte an atomaren Stufen gekennzeichnet. Dies macht sie bei der Elektrooxidation von Ethanol mindestens zweimal so aktiv und CO2‐selektiv wie käufliche Pt/C‐Katalysatoren.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.