The conventional paradigm for characterizing surface overcharging and charge reversal is based on the so-called Stern layer, in which surface dissociation reaction and specific chemical adsorption are assumed to take place. In this article, a series of Monte Carlo simulations have been applied to obtain useful insights into the underlying physics responsible for these two kinds of anomalous phenomena at the interface of two dielectrics, with special emphasis on the case of divalent counterions that are more relevant in natural and biological environments. At a weakly charged surface, it is found that independent of the type of surface charge distribution and the dielectric response of the solution, the overcharging event is universally driven by the ion size-asymmetric effect. Exceptionally, the overcharging still persists when the surface is highly charged but is only restricted to the case of discrete surface charge in a relatively low dielectric medium. As compared to the adsorption onto the homogeneously smeared charge surface that has the same average affinity for counterions, on the other hand, charge reversal under the action of a dielectric response can be substantially enhanced in the discrete surface charge representation due to strong association of counterions with interfacial groups, and the degree of enhancement depends in a nontrivial way on the reduction of the medium dielectric constant and the steric effects of finite ion size. Rather interestingly, the charge reversal is of high relevance to the overcharging of interfaces because the overwhelming interfacial association forces the coions closer to the surface due to their smaller size than the counterions. Upon the addition of a monovalent salt to the solution, the interfacial association with divalent counterions makes surface overcharging and charge reversal widely unaffected, in contrast to the prevailing notion that screening of surface charge of a homogeneous nature is determined by the competitive effects between size-exclusion effects and energetic contributions. Overall, the present work highlights that the complex interplay between the electrostatic and steric interactions should be coupled to the realistic character of surface charge to establish a faithful description of the overcharging and charge reversal at heterophase interfaces.
Monte Carlo simulations of a planar negatively charged dielectric interface in contact with a mixture of 1:1 and 3:1 electrolytes are carried out using the unrestricted primitive model under more realistic hydrated ion sizes. Two typical surface charge densities are chosen to represent the systems from the weak to strong coupling regimes. Our goal is to determine the dependence of the degree of charge inversion on increasing concentration of both mono- and trivalent salts and to provide a systematic study on this peculiar effect between short-range and electrostatic correlations. The numerical results show that addition of monovalent salt diminishes the condensation of trivalent counterions due to either the favorable solvation energy or the available space constraints. As the concentration of trivalent salt increases, on the other hand, the inclusion of the ionic size and size asymmetry results in a damped oscillatory charge inversion at low enough surface charge and another counterintuitive surface charge amplification. It is proposed that both of the anomalous events in the weak coupling regime are thought to be entropic in origin which is completely different from the electrostatic driven charge inversion in the strong coupling regime. In addition, the electrostatic images arising from the dielectric mismatch lead to a decaying depletion effect on the structure of double layer with growing salt concentration in the case of low charged interface but have no effect at high surface charge values. The microscopic information obtained here points to the need for a more quantitative theoretical treatment in describing the charge inversion phenomenon of real colloidal systems.
Employing canonical ensemble Monte Carlo simulations, we report a calculation of the distribution of small ions next to a planar negatively charged surface in the presence of mixed electrolytes of monovalent and trivalent salt ions within the framework of the primitive model under more realistic hydrated ion size conditions. The effects of surface charge discreteness and dielectric breakdown on charge inversion are discussed based on increasing concentration of both monovalent and trivalent salt. Moreover, a comparison of the simulation results for different discretization models is made along with the case of uniformly distributed charge in terms of the ionic density profiles as well as the integrated charge distribution function. For finite size charged groups located inside the lower dielectric region, a complete equivalence with the case of uniform distribution is observed if the quantities of interest are exclusively analyzed as a function of the distance to the charged interface. With protruding head groups into the aqueous solution, the excluded volume dominates over the correlation effect, therefore the ions are less accumulated in the vicinity of the charged surface, inducing that the onset position of charge inversion experiences an evident shift toward the aqueous environment. Overall, the effect of repulsive image forces on the diffuse double layer structure can be significant at low surface charge density irrespectively of surface charge distributions.
Monolayers of tungsten disulfide doped with atomic vacancies have been investigated for the first time by density functional theory calculations. The results reveal that the atomic vacancy defects affect the electronic and optical properties of the tungsten disulfide monolayers. The strongly ionic character of the W-S bonds and the non-bonding electrons of the vacancy defects result in spin polarization near the defects. Moreover, the spin polarization of single W atomic vacancies has a larger range than for one or two S atomic vacancies. In particular, increased intensity of absorption and red shift of optical absorption are universally observed in the presence of these atomic defects, which are shown to be a fundamental factor in determining the spin transport and optical absorption of tungsten disulfide monolayers
Giant charge reversal has been identified for the first time by Monte Carlo simulation for a discretely charged surface in contact with a trivalent electrolyte solution. It takes place regardless of the surface charge density under study and the monovalent salt. In stark contrast to earlier predictions based on the 2-dimensional Wigner crystal model to describe strong correlation of counterions at the macroion surface, we find that giant charge reversal reflects an intricate interplay of ionic volume effects, electrostatic correlations, surface charge heterogeneity, and the dielectric response of the confined fluids. While the novel phenomenon is yet to be confirmed with experiment, the simulation results appear in excellent agreement with a wide range of existing observations in the subregime of charge inversion. Our findings may have far-reaching implications to understanding complex electrochemical phenomena entailing ionic fluids under dielectric confinements.
The ionic density profiles and corresponding integrated charge distribution close to an aqueous interface carrying charged functional groups of different valences exposed to mixed-salt solutions of 1:1 and 3:1 electrolytes were computed by use of extensive Monte Carlo simulations within the framework of the primitive model. The influence of varying ion sizes on charge inversion was analyzed, along with the crucial role of electrostatic images arising from dielectric discontinuities. For small sizes of charged species, it was found that charge inversion is enhanced by the presence of multivalent interfacial groups. Moreover, dielectric images further intensify the degree of charge inversion despite strong depletion effects. In particular, the onset of charge inversion shifts closer to the nonaqueous phase if the surface charge density is sufficiently low. These observations are opposite to the general belief of image repulsion. When large-sized ions were considered, the degree of charge inversion was found to be independent of the structure of interfacial groups and to remain widely unaffected in the absence and presence of dielectric images. Overall, our results show that interionic excluded-volume interactions are an overwhelming factor in determining counterion condensation. In addition, the inclusion of ionic size asymmetry at weakly charged interface results in surface charge amplification, which becomes more pronounced with increasing valence of the interfacial groups. Our work emphasizes the fact that surface equilibria mainly result from a subtle balance between steric and charge correlations.
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