Most natural gas hydrate (NGH) reservoirs have poor permeability characteristics, which is unfavorable to fluid flow and gas production. To enhance gas production, a new method of radial water jet slotting and grouting (RWJSG) was proposed to reconstruct the formation around horizontal wellbores of a horizontal well. To evaluate the effectiveness of the proposed method, a three-dimensional (3D) gas production model was constructed with reference to the NGH reservoir at the SH2 site in the South China Sea (SCS). The results show that RWJSG can effectively enhance the gas recovery of the horizontal well. Compared with an unreconstructed case, the hydrate dissociation efficiency, cumulative gas production, and average ratio of gas to water production in the RWJSG case are increased by 121.0, 116.3 and 46.1%, respectively, during the 720day production period. RWJSG can enlarge reservoir exposed area, promote pressure drop transfer, and improve gas/water flow near the wellbore. In addition, the effect of increasing production mainly depends on the slot radius and number. Within a certain range, the decrease in slot spacing and increase in slot filler permeability have positive effects. For the reservoir at SH2 site, the scheme with a radius of 5 m, a spacing of 5 m, a number of 5 and a permeability of 500 mD could achieve remarkable stimulation effect. This work provides ideas and guidance for stimulation of horizontal wells in NGH reservoirs by RWJSG.

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Significant amplification of surface enhanced Raman scattering (SERS) signals can be achieved mainly by the electric field enhancement in metal core-shell nanostructures, and the enhanced magnetic field is rarely studied. In this study, our team prepared multi-gap Au/AgAu core-shell hybrid nanostructures by using gold nanocup as the core. The overgrowth processes to grow one, two, and three layers of AgAu hybrid nanoshells can produce Au/AgAu1, Au/AgAu2, and Au/AgAu3 heteronanostructures. The strong plasmon coupling between the core and shell leads to significant electromagnetic field enhancement. Under the synergistic effect of electromagnetic plasmon resonance and plasmon coupling, Au/AgAu core-shell hybrid nanostructures exhibit excellent SERS signals. We also investigate the effect of the interstitial position of the rhodamine B (RhB) molecule on Raman enhancement in Au/AgAu3 heteronanostructures. Our research can provide new ideas for the synthesis of multi-gap Raman signal amplifiers based on magnetic plasmon coupling.

Noble metal nanomaterials have many excellent optical properties due to localized surface plasmon resonance induced by external electric and magnetic fields. The plasmon-enhanced optical properties of nanomaterials can be controlled...

The trial production of natural gas hydrate reservoirs remains poor. Reasonable reservoir reconstruction, which can improve formation permeability, is an important approach to increasing the efficiency and enhancing production. In this work, water jet slotting is proposed to reconstruct an natural gas hydrate reservoir near a wellbore. The spatial slots formed by water jet slotting not only directly constitute high-permeability channels, but also generate disturbances to the surrounding in-situ sediment. Water jet slotting disturbances to nearby sediment was investigated using a three dimensional flow-structure coupling model to evaluate the proposed reconstruction method. The reservoir at the SH2 site in the Shenhu area of the South China Sea was used as the reference. A horizontal slotting arrangement along the vertical well was adopted. The results demonstrate that water jet slotting can change the primary stress state of the sediment around the wellbore, and generate a dominant stress relaxation zone and small stress concentration zone. Within the stress relaxation zone, the in-situ compressive stress was remarkably reduced or even transformed into tensile stress, accompanied by sediment displacement and volumetric expansion strain. This is conducive to loosening the sediment around the wellbore and improving the permeability characteristics. In addition, the influence of the water jet slotting parameters including slot radius, spacing, and number on disturbances to the nearby sediment was studied. Reservoir responses to water jet slotting under balanced and unbalanced bottom-hole pressures were compared and analyzed. This study provides a reference for natural gas hydrate reservoir reconstruction using water jet slotting.

The cooperation of magnetic and electric plasmon resonances in Au open nanoshells exhibits significant capability for second-harmonic generation (SHG) enhancement, and the SHG intensity is further enhanced by the Ag/Au and AuAg/Ag/Au open nanoshells.