The nepenthes-inspired lubricant-infused surface (LIS) is emerging as a novel repellent surface with self-healing, self-cleaning, pressure stability and ultra-slippery properties. Recently, stimuli-responsive materials to construct a smart LIS have broadened the application of LIS for droplet manipulation, showing great promise in microfluidics. This review mainly focuses on the recent developments towards the droplet manipulation on LIS with different mechanisms induced by various external stimuli, including thermo, light, electric, magnetism, and mechanical force. First, the droplet condition on LIS, determined by the properties of the droplet, the lubricant and substrate, is illustrated. Droplet manipulation via altering the droplet regime realized by different mechanisms, such as varying slipperiness, electrostatic force and wettability, is discussed. Moreover, some applications on droplet manipulation employed in various filed, including microreactors, microfluidics, etc., are also presented. Finally, a summary of this work and possible future research directions for the transport of droplets on smart LIS are outlined to promote the development of this field.

Slippery liquid-infused porous surface (SLIPS) is a rising star in corrosion protection owing to its outstanding corrosive medium resistance and self-healing property. The large-area and facile fabrication of SLIPS remains a challenge lying on the way of its practical application. Herein, we develop a novel SLIPS based on a porous polyvinylidene fluoride (PVDF) substrate fabricated by thermally induced phase separation. A sphere-packing structure can be easily obtained by blade-coating followed by cooling. The SLIPS exhibits an extremely low sliding angle of 5.8 so that it can resist the fouling of even the Chinese ink, ascribing to its slippery dynamic surface with low surface energy. We also evaluated the anti-corrosion performance of the SLIPS and superhydrophobic PVDF coating by electrochemical impedance spectroscopy (EIS) and scanning Kelvin probe technique (SKP), both of which exhibited enhanced corrosion resistance in 3.5 wt% NaCl solution due to the physical oil and air barriers against the corrosive medium penetration. Nevertheless, the SLIPS coatings performed outstanding self-healing properties because of the high fluidity of infused oil to recover the surface damages, and the self-healing process was recorded by the SKP.