Tandem organic solar cells are based on the device structure monolithically connecting two solar cells to broaden overall absorption spectrum and utilize the photon energy more efficiently. Herein, we demonstrate a simple strategy of inserting a double bond between the central core and end groups of the small molecule acceptor Y6 to extend its conjugation length and absorption range. As a result, a new narrow bandgap acceptor BTPV-4F was synthesized with an optical bandgap of 1.21 eV. The single-junction devices based on BTPV-4F as acceptor achieved a power conversion efficiency of over 13.4% with a high short-circuit current density of 28.9 mA cm−2. With adopting BTPV-4F as the rear cell acceptor material, the resulting tandem devices reached a high power conversion efficiency of over 16.4% with good photostability. The results indicate that BTPV-4F is an efficient infrared-absorbing narrow bandgap acceptor and has great potential to be applied into tandem organic solar cells.
Organic solar cells (OSCs) have recently reached a remarkably high efficiency and become a promising technology for commercial application. However, OSCs with top efficiency are mostly processed by halogenated solvents and with additives that are not environmentally friendly, which hinders largescale manufacture. In this study, high-performance tandem OSCs, based on polymer donors and two small-molecule acceptors with different bandgaps, are fabricated by solution processing with non-halogenated solvents without additive. Importantly, the two active layers developed from non-halogenated solvents show better phase segregation and charge transport properties, leading to superior performance than halogenated ones. As a result, a tandem OSC with high efficiency of up to 16.67% is obtained, showing unique advantages in future massive production.
Reducing the energy loss of sub-cells is critical for high performance tandem organic solar cells, while it is limited by the severe non-radiative voltage loss via the formation of non-emissive triplet excitons. Herein, we develop an ultra-narrow bandgap acceptor BTPSeV-4F through replacement of terminal thiophene by selenophene in the central fused ring of BTPSV-4F, for constructing efficient tandem organic solar cells. The selenophene substitution further decrease the optical bandgap of BTPSV-4F to 1.17 eV and suppress the formation of triplet exciton in the BTPSV-4F-based devices. The organic solar cells with BTPSeV-4F as acceptor demonstrate a higher power conversion efficiency of 14.2% with a record high short-circuit current density of 30.1 mA cm−2 and low energy loss of 0.55 eV benefitted from the low non-radiative energy loss due to the suppression of triplet exciton formation. We also develop a high-performance medium bandgap acceptor O1-Br for front cells. By integrating the PM6:O1-Br based front cells with the PTB7-Th:BTPSeV-4F based rear cells, the tandem organic solar cell demonstrates a power conversion efficiency of 19%. The results indicate that the suppression of triplet excitons formation in the near-infrared-absorbing acceptor by molecular design is an effective way to improve the photovoltaic performance of the tandem organic solar cells.
A new photonic approach of microwave waveform generator based on time-domain synthesis is proposed and experimentally demonstrated, in which two single-drive Mach-Zehnder modulators biased at quadrature point are severed as optical pulse carvers and various microwave waveforms can be generated by carving and overlapping optical field envelopes. The theoretical analysis and simulation are developed. In experiment, a square waveform with 50% duty cycle, triangular waveform with full duty cycle, and sawtooth (or reversed-sawtooth) waveform with 50% duty cycle are generated. Furthermore, a frequency doubling sawtooth (or reversed-sawtooth) waveform with full duty cycle is also obtained.
Narrow-band-gap
organic semiconductors have emerged as appealing
near-infrared (NIR) sensing materials by virtue of their unique optoelectronic
properties. However, their limited carrier mobility impedes the implementation
of large-area, dynamic NIR sensor arrays. In this work, high-performance
inorganic–organic hybrid phototransistor arrays are achieved
for NIR sensing, by taking advantage of the high electron mobility
of In2O3 and the strong NIR absorption of a
BTPV-4F:PTB7-Th bulk heterojunction (BHJ) with an enhanced photogating
effect. As a result, the hybrid phototransistors reach a high responsivity
of 1393.0 A W–1, a high specific detectivity of
4.8 × 1012 jones, and a fast response of 0.72 ms to
NIR light (900 nm). Meanwhile, an integrated 16 × 16 phototransistor
array with a one-transistor–one-phototransistor (1T1PT) architecture
is achieved. On the basis of the enhanced photogating effect, the
phototransistor array can not only achieve real-time, dynamic NIR
light mapping but also implement image preprocessing, which is promising
for advanced NIR image sensors.
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