A novel open-framework copper borovanadate, with a 6-connected topological net and 1D 8-membered ring channels, has been obtained for the first time. The compound not only exhibits a unique -B O (OH)-Cu-B(OH) linkage and features the largest ratio between TM (Cu ) and the borovanadate anion, but also possesses enhanced catalytic performance, high recyclability, and stability during the oxidation of benzylic C-H bonds.
A new dinuclear bismuth(III) coordination polymer {[Bi(H2O)]2(C7H3NO4)2(C12H8N2)2(N3)2·2H2O}n(1) containing three types of ligands has been synthesized using a solvothermal method and characterized by infrared (IR) spectroscopy, energy-dispersive X-ray spectroscopy, and X-ray single-crystal structural analysis. The compound can be viewed as a three-dimensional supramolecular network that is constructed by Bi3+cations, N3−anions, pyridine-2,5-dicarboxylate (2,5-pdc2−), and 1,10-phenanthroline (phen) ligands. Moreover, the luminescence properties, quantum yield, luminescence decay, and thermal stabilities of1were also investigated.
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