The photostability issue of CsPbX3 (X = Cl, Br, I) quantum dots (QDs) is one of the key origins for the degradation of their luminescence performance, which hinders their application in lighting and displays. Herein, we report a new method combining doping and ligand engineering, which effectively improves the photostability of CsPbBr3 QDs and the performance of QD light-emitting diodes (QLEDs). In this method, ZnBr2 is doped into CsPbBr3 QDs to reduce surface anion defects; didodecyldimethyl ammonium bromide (DDAB) and tetraoctylammonium bromide (TOAB) hybrid ligands, which have strong adsorption with QDs, are employed to protect the surface and enhance the conductivity of QD layer in QLEDs. The photoluminescence (PL) and transmission electron microscopy measurements prove the effectively improved photostability of CsPbX3 QDs. Moreover, reduced defects and improved conductivity by doping and hybrid ligands treatment also enable the improved electroluminescence performance of CsPbX3 QDs. The maximum luminance and external quantum efficiency of the QLED with optimized CsPbX3 QDs are 3518.9 cd m−2 and 5.07%, which are 3.6 and 2.1 times than that of the control device, respectively. Combining doping and hybrid ligands makes perovskite QDs have an extremely promising prospect in future applications of high-definition displays, high-quality lighting, as well as solar cells.
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This paper explores the impact of leadership empowerment behavior on employee task performance and the moderation of employee maturity in it, based on conservation of resources theory. By analyzing 308 valid questionnaires through polynomial regression analysis, the research shows that (1) leadership empowerment behavior has a positive impact on task performance; (2) employee maturity moderates the relationship between leadership empowerment behavior and task performance. This research constructs the influence path of leadership empowerment behavior on employee task performance, reveals the moderation of employee maturity, and provides insights into the leadership behavior practices of Chinese enterprise managements.
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