A mild aerobic cross-dehydrogenative coupling between N-heteroarenes and benzylic C(sp3)-H bond has been achieved through the visible-light-induced photocatalysis. This approach provides a sustainable alternative to Minisci benzylation reactions with readily...
A visible-light/nickel dual catalyzed stoichiometric coupling of methylarenes via bromine radical-enhance HAT has been developed. Aryl bromides serve as both cross-coupling partners and bromine radical precursor. Mechanistic studies reveal that...
A visible-light-mediated oxidative cyclization of N-arylacrylamides by a radical cascade with readily available aliphatic or aromatic aldehydes was achieved. The transformation provides an operational, mild, and efficient access to various...
Herein, we report a visible‐light‐mediated hydroalkylation reaction of alkenes using easily available aldehydes as alkyl sources via bromo radical‐promoted photoredox decarbonylation. This protocol provides an alternative entry to C(sp3)−C(sp3) bond formation and features considerable advantages including mild and clean reaction conditions, obviation for transition‐metal catalyst, and good functional group compatibility.
An efficient base-promoted aerobic oxidation procedure for the synthesis of fused 1,3,5-triazines from 2-aminobenzimidazoles, aromatic aldehydes and ammonium iodide has been developed. In this multi-component protocol, ammonium iodide served as...
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