The Cu(i)-catalyzed mechanism of 5-enamined-functionalized fully substituted 1,2,3-triazole synthesis was rationalized by interrupted copper(i)-catalyzed terminal alkynes and organic azides click reaction (CuAAC).

The matrix isolation infrared spectroscopic and quantum chemical calculation results indicate that tungsten oxo and mono-superoxide, WO3 and (η2-O2)­WO2, coordinate noble gas atoms in forming noble gas–tungsten oxide complexes. The results showed that both WO3 and (η2-O2)­WO2 oxides can coordinate one Ar or Xe atom in solid noble gas matrixes; otherwise, tungsten mono- and dioxides cannot. Hence, the WO3 and (η2-O2)­WO2 molecules trapped previously in solid argon noble gas matrixes should be regarded as the WO3(Ar) oxide and (η2-O2)­WO2(Ar) peroxide complexes. When annealing, the lighter Ar atom can be replaced by a heavier xenon atom to form WO3(Xe) and (η2-O2)­WO2(Xe) complexes. What’s more, upon UV photolysis, both Ar and Xe atoms can be replaced by oxygen to form a tungsten disuperoxide (η2-O2)2WO2 complex. The binding energies were predicted to be 25.7, 16.6, 9.4, 14.7, and 8.1 kcal/mol for the (η2-O2)2WO2, WO3(Xe), WO3(Ar), (η2-O2)­WO2(Xe), and (η2-O2)­WO2(Ar) complexes at the CCSD­(T)//M06-2X-D3//def2-TZVP/DGDZVP/SDD level. The substitution law, O2 > Xe > Ar, can be interpreted according to the chemical reaction energies calculated to be −6.6 and +11.0 kcal/mol, respectively, for the equation formulas Xe + (η2-O2)­WO2(Ar) = (η2-O2)­WO2(Xe) + Ar and O2 + (η2-O2)­WO2(Xe) = (η2-O2)2WO2 + Xe at the same level.