This paper reports our recent investigations in the synthesis, characterization, and solution self-assembly of giant gemini surfactants consisting of two hydrophilic carboxylic acid-functionalized polyhedral oligomeric silsesquioxane (APOSS) heads and two hydrophobic polystyrene (PS) tails covalently linked via a rigid spacer (p-phenylene or biphenylene) (PS-(APOSS) 2 -PS). The sequential "click" approach was employed in the synthesis, which involved thiol-ene mono-functionalization of vinyl-functionalized POSS, Cu(I)catalyzed Huisgen [3 + 2] azide-alkyne cycloadditions for "grafting" polymer tails onto the POSS cages, and subsequent thiol-ene "click" surface functionalization. The study of their self-assembly in solution revealed a morphological transition from vesicles to wormlike cylinders and further to spheres as the degree of ionization of the carboxylic acid groups on POSS heads increases. It was found that the PS tails are generally less stretched in the micellar cores of these giant gemini surfactants than those of the corresponding single-tailed (APOSS-PS) giant surfactant. It was further observed that the PS tail conformations in the micelles were also affected by the length of the rigid spacers where the one with longer spacer exhibits even more stretched PS tail conformation. Both findings could be explained by the topological constraint imposed by the short rigid spacer in PS-(APOSS) 2 -PS gemini surfactants. This constraint effectively increases the local charge density and leads to an anisotropic head shape that requires a proper re-distribution of the APOSS heads on the micellar surface to minimize the total electrostatic repulsive free energy. The study expands the scope of giant molecular shape amphiphiles and has general implications in the basic physical principles underlying their solution self-assembly behaviors.

An all-fiber optic catheter-based polarization-sensitive optical coherence tomography system is demonstrated. A novel multiplexing method was used to illuminate the sample, splitting the light from a 58.5kHz Fourier-domain mode-locked laser such that two different polarization states, alternated in time, are generated by two semiconductor optical amplifiers. A 2.3mm forward-view cone-scanning catheter probe was designed, fabricated, and used to acquire sample scattering intensity and phase retardation images. The system was first verified with a quarter-wave plate and then by obtaining intensity and phase retardation images of high-birefringence plastic, human skin in vivo, and untreated and thermally ablated porcine myocardium ex vivo. The system can potentially in vivo image of the cardiac wall to aid radio-frequency ablation therapy for cardiac arrhythmias.

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Collinear calibration is a typical and common method for a laser (heterodyne) interferometer, but it usually suffers from the influence of the tilt of the target retroreflectors and the dissymmetry of the optical paths during the calibration. This paper mainly analyzes and models the calibration error caused by the tilt error of the target retroreflectors and reveals the error source that is the disturbance from the rotary error of the guideway slider pair. Experimental results prove the validity of the analysis and model of the calibration error. The calibration error is up to 0.5 μm when the tilt error is 0.36°, which is large enough to equal the maximum tolerance of laser interferometer (0.5 μm) in use.

Supersonic gas-jet target performs an important role in laser wakefield acceleration, and its density diagnosis is a significant part of target characteristic study. In this paper, a Mach–Zehnder and Nomarski interference system is set up and used for gas-jet target density diagnosis. We have investigated and compared the performance of the Mach–Zehnder part and Nomarski part. The feasibility of the Nomarski interferometer with vertical fringes has been verified. Moreover, it shows better stability and has a more compact structure, beneficial for obtaining more accurate and effective target density characterization in laser wakefield acceleration.