An atom-economic synthetic method is developed to access CPP materials used for photocatalytic H2 production from H2O, and the PHP reaction can be greatly accelerated by DMF cosolvent, leading to an HER of 15 975 μmol g−1 h−1 without the aid of Pt.

Solvent-exfoliated CPP-based photocatalysts have been innovatively used for photocatalytic hydrogen production with an unprecedented HER of up to 303.7 mmol h−1 g−1.

3,4-ethylene dioxythiophene (EDOT), as a monomer of commercial conductive poly(3,4-ethylene dioxythiophene) (PEDOT), has been facilely incorporated into a series of new π-conjugated polymer-based photocatalysts, i.e., BSO2-EDOT, DBT-EDOT, Py-EDOT and DFB-EDOT,...

In this contribution, we developed a simple, scalable, and universal strategy to exfoliate conjugated porous polymers (CPPs) into 2D nanosheets. A series of pyrenyl (Py)-, bezene(B)-, thienyl (T)-, thieno[3,2-b]thiophene (Tt)-...