The fiberboard waste with about 10% adhesive as bonding materials will release a large amount of NO x into the atmosphere when being used for energy resources. To mitigate the emission, it is desirable to convert the waste biomass into material-based products, so that the N species could be possibly retained in the solids without being emitted into the air. Thus, this study aims to examine the effects of glucose addition on the N retention and migration in chars during the copyrolysis with fiberboard wastes, especially considering the N-doped solid char as a potential high value functional carbon material. The pyrolysis experiments were mainly conducted in a fixed-bed quartz reactor at various temperatures, and the resultant chars were subjected to XPS analysis and other characterizations. It was found that the introduction of glucose has significantly increased the N retentions by 2−3 times at all the examined temperatures compared to the pyrolysis of fiberboard alone. During the copyrolysis, the relative abundance of amine-N in char at 400 °C has greatly decreased, while 500 °C has seen only N-5 and N-6 remaining in the char. Therefore, the copyrolysis of fiberboard waste and glucose could considerably enhance the N retentions in chars as well as vary the transformation of N occurring forms by the reactions between the adhesive-derived volatiles and the O-containing groups from the decomposition of glucose.
Cap-and-trade regulation provides incentives for manufacturers to reduce carbon emissions, but manufacturers' insufficient capital can disrupt the implementation of low-carbon emission reduction technologies. To alleviate capital constraints, manufacturers can adopt external financing for low-carbon emission reduction investments. This paper studies the independent financing and financing cooperation behavior in a supply chain in which the manufacturer and retailer first implement low-carbon emission reduction technologies and then organize production and sales in accordance with wholesale price contracts. Through comparing the optimal profits and low-carbon emission reduction levels under the independent financing and financing cooperation mode, we come to the following conclusions: (1) Although financing interest increases the cost of the supply chain, manufacturers prefer to invest in reducing carbon emissions rather than buying carbon quotas. (2) When financing independently, a decentralized decision-making mode (MD) is the best choice for manufacturers. (3) In cooperative financing, when the supply chain adopts a decentralized decision-making mode (SD) in which the retailer determines the financing cost-sharing ratio according to their optimal profit, the profits of the supply chain and its members are significantly improved. (4) When manufacturers and retailers adopt a centralized decision-making model (SC) in cooperative financing, they jointly determine the financing cost-sharing ratio and the level of low-carbon emission reduction. If the financing cost-sharing ratio meets a certain threshold range, the profits of manufacturers and retailers achieve Pareto improvement, indicating that this cooperative financing model is effective.
The Persulfate-based advanced oxidation process is the most efficient and commonly used technology to remove organic contaminants in wastewater. Due to the large surface area, unique electronic properties, abundant N functional groups, cost-effectiveness, and environmental friendliness, N-doped biochars (NBCs) are widely used as catalysts for persulfate activation. This review focuses on the NBC for oxidative degradation of organics-contaminated wastewater. Firstly, the preparation and modification methods of NBCs were reviewed. Then the catalytic performance of NBCs and modified NBCs on the oxidation degradation of organic contaminants were discussed with an emphasis on the degradation mechanism. We further summarized the detection technologies of activation mechanisms and the structures of NBCs affecting the PS activation, followed by the specific role of the N configuration of the NBC on its catalytic capacity. Finally, several challenges in the treatment of organics-contaminated wastewater by a persulfate-based advanced oxidation process were put forward and the recommendations for future research were proposed for further understanding of the advanced oxidation process activated by the NBC.
To improve the tribological performance of the seal rings in the dry gas seal, the elliptical microtextures with different inclination angles (0°, 45°, 90°, 135°) were processed on the end face of SiC static rings by nanosecond laser. Diamond-like carbon (DLC) films were then deposited on the microtextured end face. Under dry friction condition, the end-face friction and wear test was conducted to simulate the actual working state of the dry gas seal at start-up phase. The effects of micro-texture inclination angles and DLC phase change on the tribological properties of seal rings were investigated. The possible friction reduction mechanism was analyzed. The results show that compared with the smooth surface, the elliptical micro-texture can effectively improve the tribological properties of DLC films. At the same time, the inclination angle of the elliptical micro-texture has a remarkable influence on the tribological properties. When the micro-texture inclination angle is 90°, the static ring sample has the best friction reduction and wear resistance performance. Compared with the untextured sample, the average friction coefficient is reduced by 46.15%. The wear reduction characteristics of the textured end face are mainly contributed to the capturing effect of the texture on wear particles.
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