Self-lubricating polymer composite coatings, with tailorable tribological and mechanical properties, have been widely employed on mechanical parts to reduce friction and wear, which saves energy and improves the overall performance for applications such as aerospace satellite parts, shafts, gears, and bushings. The addition of functional fillers can overcome the limitations of single-polymer coatings and extend the service life of the coatings by providing a combination of low friction, high wear resistance, high load bearing, high temperature resistance, and high adhesion. This paper compares the heat resistance, and the tribological and mechanical properties of common polymer matrices, as well as the categories of functional fillers that improve the coating performance. Applicable scopes, process parameters, advantages, and limitations of the preparation methods of polymer coatings are discussed in detail. The tribological properties of the composite coatings with different matrices and fillers are compared, and the lubrication mechanisms are analyzed. Fillers reduce friction by promoting the formation of transfer films or liquid shear films. Improvement of the mechanical properties of the composite coatings with fillers of different morphologies is described in terms of strengthening and toughening mechanisms, including a stress transfer mechanism, shear yielding, crack bridging, and interfacial debonding. The test and enhancement methods for the adhesion properties between the coating and substrate are discussed. The coating adhesion can be enhanced through mechanical treatment, chemical treatment, and energy treatment of the substrate. Finally, we propose the design strategies for high-performance polymer composite coating systems adapted to specific operating conditions, and the limitations of current polymer composite coating research are identified.
We have achieved an on-surface synthesis of giant conjugated macrocycles having a diameter of % 7 nm and consisting of up to 30 subunits. The synthesis started with a debrominative coupling of the molecular precursors on a hot Ag(111) surface, leading to the formation of arched oligomeric chains and macrocycles. These products were revealed by scanning tunneling microscopy in combination with density functional theory to be covalent oligomers. These intermediates also display C-Ag organometallic bonds between parallel molecular subunits due to site-selective debromination and the asymmetric molecular conformation. Subsequent cyclodehydrogenation at higher temperatures steered the final conjugation of the macrocycles. Our findings provide a novel design strategy toward p-conjugated macrocycles and open up new opportunities for the precise synthesis of organic nanostructures.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.