The gel properties and structural changes of sweet potato starch induced by heat-moisture treatment (HMT) were investigated, and its vermicelli textural properties were revealed. HMT increased the relative crystallinity, and the crystallinity reduced with increasing moisture content, which was consistent with the results of DSC. RVA results revealed that the HMT starches showed an increased setback viscosity and a reduced breakdown viscosity, indicating that the HMT starches gel lead a stronger retrogradation tendency. Rheometer results indicated that the HMT starches had a stronger elasticity behavior. The content of amylose of starch and the possible amylose fine molecular change during HMT at different water content were hypothesized, and this caused the gel properties of starch. Consequently, the HMT starch vermicelli exhibited higher hardness, springiness, and chewiness. These mechanistic relations among starch structure, gel properties, and vermicelli quality during HMT will provide useful information for the starch vermicelli industry.
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