In this work, a novel amino-functionalized mesoporous microsphere was synthesized to remove cadmium ions from water. The Fe 3 O 4 @SiO 2 @m-SiO 2 -NH 2 micro-spheres were successfully prepared via a facile two-stage process by coating of the as-synthesized magnetic cores with a silica shell followed by increasing the porosity of the structure using a cationic surfactant as structure-directing agents. The template removal from the structure has been performed following the method of solvent extraction and methanolenhanced supercritical fluid CO2 (SCF-CO2) extraction. This novel approach provides the multifunctional microspheres with a high surface area, which improves the adsorption capacity of adsorbent.Characterization of the as-synthesized adsorbent were analytically determined showing that as-prepared adsorbent has a significant surface area of 637.38 m 2 g -1 . The kinetic data agreed with pseudo-second-order model and Langmuir isotherm. The maximum adsorption capacity of the synthesized adsorbent was about 884.9 mg g -1 , and can be easily separated from solution under an external magnetic field. The synthesized microspheres were recycled using HCl and cadmium removal was over 92% after 6 cycles, which confirms the chemical stability and reusability of the manufactured particles.

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This paper investigates the adsorption of nitrate anions from aqueous solutions on ammoniumfunctionalized magnetic mesoporous silica. The adsorbent was prepared via two-step coating process of silica on magnetic core (Fe3O4). The resultant structure was modified by 3-aminopropyl triethoxysilane (APTES), and finally acidified in HCl solution to convert the grafted amino groups to ammonium ones. Field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), vibration sample magnetometer (VSM), Energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FT-IR), and N2 adsorption/desorption were used to characterize the obtained samples. Experimental results showed that several factors affected the uptake behavior such as pH, contact time, and initial concentration of nitrate. The amount of sorbent loading were examined and the adsorbent shows great adsorption capacity for NO3¯ (ca.51.28 mg g -1 at 25 °C ). The nitrate loaded multifunctional microsphere can be easily regenerated with NaOH solution. The separation of multifunctional magnetic microspheres from solution by novel high gradient magnetic separation (HGMS), using the collection of rods, was also investigated in details. Contrast to other methods based on filter and batch conditions, large volumes of water can be easily handled by the new designed HGMS due to the decreasing pressure drop and retention times. The effect of a set of two different experimental variables, i.e. flowrate and magnetic field strength, were investigated to identify the best working conditions for the separation of adsorbent from treated water. The most efficient backwash system was offered to reuse the magnetic particles, too. The removal efficiency of NO3¯ from solution was around 86.24% by the constructed HGMS under the optimal experimental conditions of 7.5 mL s -1 flowrate and: 3.49 mT magnitude of the magnetic field.

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