Purpose
Polymeric particulate composites with thermoplastics, especially polypropylene (PP) matrix with mineral fillers, are of great practical importance due to their simple possibility of modifying mechanical properties and reducing the price/volume ratio of the resulting material. Both filler properties and interface properties have a great effect on the mechanical properties, primarily on stiffness and toughness, of the resulting composite material. Good final dispersion of the filler particles also plays a very important role. To reach the best adhesion and distribution of the particles, various procedures are carried out for activation of the particles. Therefore, the purpose of this paper is to investigate and discuss the effect of using plasma as a tool for treating commercially available CaCO3 nanoparticles in PP matrix.
Design/methodology/approach
The effect of the composite structure on its mechanical properties was studied from an experimental as well as a theoretical point of view. For an experimental study, four PP matrix were chosen. For use as filler, the commercially available precipitated surface-treated calcium carbonate was chosen. The composites were prepared with 5, 10, and 15 wt% of fillers. The sequence of expositions of plasma was chosen to verify the optimal treatment duration. The filler particles were characterized by several structure analytical methods. The composite mechanical properties were characterized by tensile, bending, impact, and creep tests. The deformation behavior of the three-phase composite with homogeneously distributed coated particles was numerically simulated on a microscopic scale.
Findings
The main conclusions of this work can be summarized as follows: with the use of plasma to the precipitated calcium carbonate, composites with well-dispersed particles can be prepared; the surface modification using plasma is done mainly by grafting –OH groups onto the particles’ surface; a synergetic effect of modifier enhancing the performance was observed; performance modifier increases the resistance against viscoelastic strain; and the size of the particles and their volume content generally lead to increase in the macro modulus of the composite.
Originality/value
Plasma, as a tool for treating the inorganic fillers, enables to destroy the agglomerates in composite, which is the basic way on how to optimally utilize the synergetic effect of composite with PP matrix.
This paper is focused on an analysis of a multilayer ceramic-based piezoelectric vibration energy harvester, which could be excited by ambient vibrations or external forces and thus provide a useful source of electricity for modern electronics. The proposed multilayer concept of the energy harvester enables introduction of tensile / compressive residual stresses inside particular layers. These stresses are intended to be used for enhancement of the harvester ́s fracture resistance and simultaneously for the improvement of the energy gain upon its operation. A crack arrest, by means of compressive residual stresses (in the outer “non-piezo” layer), will be utilized to this end. Primarily, the extended classical laminate theory (taking into account the piezoelectric characteristics of selected layers) will be used to define various designs of particular layers with various levels of residual stresses inside them. The weight function method is subsequently employed to select a design, which is most resistant to propagation of preexisting cracks. Selected laminate configurations are verified by means of FE simulations. Such analysis is essential for development of new energy harvesting systems formed of new smart materials and structures, which could be integrated in future development processes.
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