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A simple method for the preparation of bromoferrocenes from stannylferrocenes is described: the preparation of 1,1′-dibromoferrocene is used as an example. Stannylferrocenes are reacted with bromine directly in dichloromethane to give bromoferrocenes in a self-indicating titration reaction. Also, an enhanced method of removal of the highly soluble organotin tin by-products formed in the preparation of 1,1′-diiodoferrocene from 1,1′-tri- n -butylstannylferrocene is reported allowing the preparation of large-scale quantities of 1,1′-diiodoferrocene, which is one of the most important starting materials in ferrocene chemistry.

Catalysts assemble! We present the design and synthesis of a large family of amino acid derived guanidine organic moieties as catalysts in the solution state and building blocks towards extended H-bonded architectures upon crystallisation.

The absolute stereochemistry of the marine alkaloid (+)-(R)-tiruchanduramine was established via a convergent total synthesis in six steps and 15.5% overall yield from Fmoc-D-Dab(Boc)-OH.

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