The metalized optical fiber tip was used to generate thermal wave instead of metal foil attached to a tube as in the case of conventional thermal wave resonance cavity (TWRC) technique. The liquid thermal diffusivity was obtained through scanning the cavity length by moving this tip with respect to pyroelectric detector in liquid media, in a thermally thick region. Three-dimensional treatment of the metalized fiber tip was reduced to one-dimensional treatment using diameter of thermal wave generator relatively bigger than that of laser spot size. This applicability can be seen in two diameter size of optical fiber where the thermal diffusivity value of water obtained by this technique agrees with the values obtained by the conventional TWRC technique. This technique has a potential to be used in measuring thermal diffusivity of small liquid volume.
Two different concentrations of CdCl2 and (NH2)2CS were used to prepare CdS thin films, to be deposited on glass substrate by chemical bath deposition (CBD) technique. CdCl2 (0.000312 M and 0.000625 M) was employed as a source of Cd2+ while (NH2)2CS (0.00125 M and 0.000625 M) for S2− at a constant bath temperature of 70 °C. Adhesion of the deposited films was found to be very good for all the solution concentrations of both reagents. The films were air-annealed at a temperature between 200 °C to 360 °C for one hour. The minimum thickness was observed to be 33.6 nm for film annealed at 320 °C. XRD analyses reveal that the films were cubic along with peaks of hexagonal phase for all film samples. The crystallite size of the films decreased from 41.4 nm to 7.4 nm with the increase of annealing temperature for the CdCl2 (0.000312 M). Optical energy band gap (Eg), Urbach energy (Eu) and absorption coefficient (α) have been calculated from the transmission spectral data. These parameters have been discussed as a function of annealing temperature and solution concentration. The best transmission (about 97%) was obtained for the air-annealed films at higher temperature at CdCl2 (0.000312 M).
The pulsed laser thermal lens technique was used to study the thermal diffusivity of fluids containing copper nanoparticles (Cu-NPs) prepared by γ-irradiation method. The samples were prepared for the different concentrations of Cu precursor at 20.KGy dose. A Q-switched Nd-YAG pulsed laser of wavelength 532.nm was used as an excitation source and He-Ne laser was used as a probe beam in the present thermal lens experiment. It was found that the thermal diffusivity of the solution depends on the density of Cu-NPs.
The thermal lens technique was utilized in silver nanofluid containing silver nanoparticles in polyvinylpyrrolidone solution to study the effect of nanoparticle size on thermal diffusivity. The different sizes of silver nanoparticles were prepared by irradiating the solution of silver nitrate in polyvinylpyrrolidone with respective dose of γ-radiation. The average sizes of particle in the prepared samples were measured using nanophox machine. The thermal lens measurement was carried out by using a diode laser of wavelength 514 nm and a He–Ne laser for the excitation source and the probe beam, respectively. The obtained result showed a decrease in the thermal diffusivity of nanofluid with the decrease in particle size.
Thin and transparent films of doped cadmium sulfide (CdS) were obtained on commercial glass substrates by Chemical Bath Deposition (CBD) technique. The films were doped with low concentration of Sn, and annealed in air at 300 °C for 45 min. The morphological characterization of the films with different amounts of dopant was made using SEM and EDAX analysis. Optical properties of the films were evaluated by measuring transmittance using the UV-vis spectrophotometer. A comparison of the results revealed that lower concentration of Sn doping improves transmittance of CdS films and makes them suitable for application as window layer of CdTe/CIGS solar cells.
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