Zinc-air batteries have attracted much attention and received revived research efforts recently due to their high energy density, which makes them a promising candidate for emerging mobile and electronic applications. Besides their high energy density, they also demonstrate other desirable characteristics, such as abundant raw materials, environmental friendliness, safety, and low cost. Here, the reaction mechanism of electrically rechargeable zinc-air batteries is discussed, different battery configurations are compared, and an in depth discussion is offered of the major issues that affect individual cellular components, along with respective strategies to alleviate these issues to enhance battery performance. Additionally, a section dedicated to battery-testing techniques and corresponding recommendations for best practices are included. Finally, a general perspective on the current limitations, recent application-targeted developments, and recommended future research directions to prolong the lifespan of electrically rechargeable zinc-air batteries is provided.
A highly selective and durable electrocatalyst for carbon dioxide (CO2) conversion to formate is developed, consisting of tin (Sn) nanosheets decorated with bismuth (Bi) nanoparticles. Owing to the formation of active sites through favorable orbital interactions at the Sn‐Bi interface, the Bi‐Sn bimetallic catalyst converts CO2 to formate with a remarkably high Faradaic efficiency (96%) and production rate (0.74 mmol h−1 cm−2) at −1.1 V versus reversible hydrogen electrode. Additionally, the catalyst maintains its initial efficiency over an unprecedented 100 h of operation. Density functional theory reveals that the addition of Bi nanoparticles upshifts the electron states of Sn away from the Fermi level, allowing the HCOO* intermediate to favorably adsorb onto the Bi‐Sn interface compared to a pure Sn surface. This effectively facilitates the flow of electrons to promote selective and durable conversion of CO2 to formate. This study provides sub‐atomic level insights and a general methodology for bimetallic catalyst developments and surface engineering for highly selective CO2 electroreduction.
This review summarizes recent research progress and perspectives on bi-functional oxygen electrocatalysts active towards oxygen reduction and oxygen evolution reactions for rechargeable metal–air batteries.
Combining the advantages of homogeneous and heterogeneous catalysts,s ingle-atom catalysts (SACs) are bringing new opportunities to revolutionizeO RR catalysis in terms of cost, activity and durability.However,the lack of highperformance SACs as well as the fundamental understanding of their unique catalytic mechanisms call for serious advances in this field. Herein, for the first time,w ed evelop an Ir-N-C single-atom catalyst (Ir-SAC) whichm imics homogeneous iridium porphyrins for high-efficiency ORR catalysis.I na ccordance with theoretical predictions,the as-developed Ir-SAC exhibits orders of magnitude higher ORR activity than iridium nanoparticles with arecord-high turnover frequency (TOF) of 24.3 e À site À1 s À1 at 0.85 Vv s. RHE) and an impressive mass activity of 12.2 Amg À1 Ir ,which far outperforms the previously reported SACs and commercial Pt/C.A tomic structural characterizations and density functional theory calculations reveal that the high activity of Ir-SACi sa ttributed to the moderate adsorption energy of reaction intermediates on the mononuclear iridium ion coordinated with four nitrogen atom sites.
Rational construction of atomic‐scale interfaces in multiphase nanocomposites is an intriguing and challenging approach to developing advanced catalysts for both oxygen reduction (ORR) and evolution reactions (OER). Herein, a hybrid of interpenetrating metallic Co and spinel Co3O4 “Janus” nanoparticles stitched in porous graphitized shells (Co/Co3O4@PGS) is synthesized via ionic exchange and redox between Co2+ and 2D metal–organic‐framework nanosheets. This strategy is proven to effectively establish highways for the transfer of electrons and reactants within the hybrid through interfacial engineering. Specifically, the phase interpenetration of mixed Co species and encapsulating porous graphitized shells provides an optimal charge/mass transport environment. Furthermore, the defect‐rich interfaces act as atomic‐traps to achieve exceptional adsorption capability for oxygen reactants. Finally, robust coupling between Co and N through intimate covalent bonds prohibits the detachment of nanoparticles. As a result, Co/Co3O4@PGS outperforms state‐of‐the‐art noble‐metal catalysts with a positive half‐wave potential of 0.89 V for ORR and a low potential of 1.58 V at 10 mA cm−2 for OER. In a practical demonstration, ultrastable cyclability with a record lifetime of over 800 h at 10 mA cm−2 is achieved by Zn–air batteries with Co/Co3O4@PGS within the rechargeable air electrode.
Transition metal atoms with corresponding nitrogen coordination are widely proposed as catalytic centers for the oxygen reduction reaction (ORR) in metal–nitrogen–carbon (M–N–C) catalysts. Here, an effective strategy that can tailor Fe–N–C catalysts to simultaneously enrich the number of active sites while boosting their intrinsic activity and utilization is reported. This is achieved by edge engineering of FeN4 sites via a simple ammonium chloride salt‐assisted approach, where a high fraction of FeN4 sites are preferentially generated and hosted in a graphene‐like porous scaffold. Theoretical calculations reveal that the FeN4 moieties with adjacent pore defects are likely to be more active than the nondefective configuration. Coupled with the facilitated accessibility of active sites, this prepared catalyst, when applied in a practical H2–air proton exchange membrane fuel cell, delivers a remarkable peak power density of 0.43 W cm−2, ranking it as one of the most active M–N–C catalysts reported to date. This work provides a new avenue for boosting ORR activity by edge manipulation of FeN4 sites.
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