Using a portable emissions measurement system, 16 gasoline passenger cars were tested on a fixed route consisting of different types of roads in Macao and the data were normalized with the vehicle-specific power bin method. The normalized HC, CO and NO X emission levels of the seven passenger car samples with model year older than 2000 were 3.19 ± 5.04, 14.59 ± 22.88, 2.57 ± 2.12 g/km, respectively. The HC, CO and NO X emission levels of other newer samples were 0.02 ± 0.02, 0.23 ± 0.29 and 0.10 ± 0.13 g/km, respectively. The scrappage of old passenger cars in Macao should be a high priority to control the total emissions of motor vehicles. Based on relative emission levels, a clear and similar pattern for gaseous pollutants and fuel consumption with driving conditions was identified. The emissions of HC, CO and NO X are best fitted to average speed with inverse functions. Fuel consumption is best fitted to average speed with a power function. Compared to the average driving conditions, the emission factors of HC, CO and NO X and fuel consumption of gasoline passenger cars during the rush hours on the Macau Peninsula will be increased by 61, 55, 45 and 90 %, respectively. This situation will deteriorate by 2015 if no further transportation management strategies are implemented in Macao. To save energy and mitigate the air pollutant emissions in the urban area, improved traffic planning and travel demand management are also necessary.
Statistical analysis of stormwater runoff data enables general identification of runoff characteristics. Six catchments with different urban surface type including roofs, roadway, park, and residential/commercial in Macau were selected for sampling and study during the period from June 2005 to September 2006. Based on univariate statistical analysis of data sampled, major pollutants discharged from different urban surface type were identified. As for iron roof runoff, Zn is the most significant pollutant. The major pollutants from urban roadway runoff are TSS and COD. Stormwater runoff from commercial/residential and Park catchments show high level of COD, TN, and TP concentration. Principal component analysis was further done for identification of linkages between stormwater quality and urban surface types. Two potential pollution sources were identified for study catchments with different urban surface types. The first one is referred as nutrients losses, soil losses and organic pollutants discharges, the second is related to heavy metals losses. PCA was proved to be a viable tool to explain the type of pollution sources and its mechanism for different urban surface type catchments.
Field monitoring of the toxic organic compounds (PCBs, PAHs, organochlorine pesticides) in the top sediments of Pearl River Estuary and its up-streams were made. It was found that the highest concentrations of these toxic organic compounds occurred in the sediment sampled at Macau inner harbor (ZB013), which is a sink of suspended fine particles transported from the upstream waterways. Because of the affinity of the hydrophobic organic compounds (PAHs, PCBs) for the solid phase, these fine particle depositions led to accumulation of these compounds in the sediment of Macau. The atmospheric dry deposition may be another source of the toxic organic pollution in the sediment.
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