BaTiO3/hyperbranched polyester/methacrylate core-shell nanoparticles were studied by varying the shell thickness and the methacrylate ratio. We demonstrated that coalescence typically observed in traditional composites employing polymer matrices is significantly reduced. By modifying the shell thickness, the equivalent filler fraction was tuned from 7 wt. % to 41 wt. %. Obtained permittivities were compared with reported models for two-phase mixtures. The nonlinear behavior of the dielectric constant as a function of the equivalent filler fraction has been fitted with the Bruggeman equation. Methacrylate groups reduce by a decade the loss factor by improving nanoparticles adhesion. The permittivity reaching 85 at 1 kHz makes core-shell nanoparticles a promising material for embedded capacitors.
Using Radio Frequency (RF) waves, magnetic resonance imaging (MRI) systems can make detailed images of human organs for accurate diagnostic processes and disease detection. The overhaul of certain electronic components has become necessary to keep up with the progress of MRI systems. Among the components responsible for image quality, the adjustable non-magnetic capacitors, also called trimmers, are of great importance. The purpose of this paper is to suggest a new design of a trimmer using non-magnetic materials, able to hold a high voltage ( >3 kV) and reach a resonance frequency above 100 MHz. Constructional analysis performed on existing commercial trimmers, combined with the electrical Finite Element Method, were carried out to propose a prototype matching the desired specifications. A dielectric shield surrounding the electrodes was sized to ensure voltage withstand. Moreover, the rotor and the worm-and-gear set were joined together to combat the vibrations generated by the MRI system. The present study includes the modelling step of the component by numerical simulation, the manufacturing, the electrical performance characterization, and the mechanical solution for tuning capacitance. The final prototype combines electrical performance corresponding to the required specifications in particular a high breakdown voltage (39.7 kV) and a resonance frequency (130 MHz).
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.