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A periodic method is used to determine simultaneously both thermal conductivity and diffusivity of various polymer materials at room temperature. The sample is placed between two metallic plates and temperature modulation is applied on the front side of one of the metallic plates. The temperature at the front and rear sides of both plates is measured and the experimental transfer function is calculated. The theoretical thermal heat transfer function is calculated by the quadrupole method. Thermal conductivity and diffusivity are simultaneously identified from both real and imaginary parts of the experimental transfer function. The thermophysical parameters of several polymer samples (PTFE, PVDF and PA11) with different thicknesses (respectively, 5 mm, 2 mm and 300 µm) were studied and compared with values from the literature. The values identified for the thermal parameters are in good agreement with values from the literature for PTFE and PVDF samples; however, we show that the method reaches its limit for the thinner PA11 sample, owing to inadequacy of the thermal model.

Abstract. An ensemble Kalman filter (EnKF) has been coupled to the CHIMERE chemical transport model in order to assimilate ozone ground-based measurements on a regional scale. The number of ensembles is reduced to 20, which allows for future operational use of the system for air quality analysis and forecast. Observation sites of the European ozone monitoring network have been classified using criteria on ozone temporal variability, based on previous work by Flemming et al. (2005). This leads to the choice of specific subsets of suburban, rural and remote sites for data assimilation and for evaluation of the reference run and the assimilation system. For a 10-day experiment during an ozone pollution event over Western Europe, data assimilation allows for a significant improvement in ozone fields: the RMSE is reduced by about a third with respect to the reference run, and the hourly correlation coefficient is increased from 0.75 to 0.87. Several sensitivity tests focus on an a posteriori diagnostic estimation of errors associated with the background estimate and with the spatial representativeness of observations. A strong diurnal cycle of both these errors with an amplitude up to a factor of 2 is made evident. Therefore, the hourly ozone background error and the observation error variances are corrected online in separate assimilation experiments. These adjusted background and observational error variances provide a better uncertainty estimate, as verified by using statistics based on the reduced centered random variable. Over the studied 10-day period the overall EnKF performance over evaluation stations is found relatively unaffected by different formulations of observation and simulation errors, probably due to the large density of observation sites. From these sensitivity tests, an optimal configuration was chosen for an assimilation experiment extended over a three-month summer period. It shows a similarly good performance as the 10-day experiment.

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International audienceIn this paper, we show how to compute an over-approximation for the reachable set of uncertain nonlinear continuous dynamical systems by using guaranteed set integration. We introduce two ways to do so. The first one is a full interval method which handles whole domains for set computation and relies on state-of-the-art validated numerical integration methods. The second one relies on comparison theorems for differential inequalities in order to bracket the uncertain dynamics between two dynamical systems where there is no uncertainty. Since the derived bracketing systems are piecewise Ck-differentiable functions, validated numerical integration methods cannot be used directly. Hence, our contribution resides in the use of hybrid automata to model the bounding systems. We give a rule for building these automata and we show how to run them and address mode switching in a guaranteed way in order to compute the over approximation for the reachable set. The computational cost of our method is also analyzed and shown to be smaller that the one of classical interval techniques. Sufficient conditions are given which ensure the epsiv-practical stability of the enclosures given by our hybrid bounding method. Two examples are also given which show that the performance of our method is very promising