A general combined hydrothermal and annealing process for the fabrication of ferrite/perovskite oxide core/shell nanostructures was introduced. The coating of a perovskite oxide (ABO 3 ) layer on spherical ferrite particles was performed in two steps. A dense and smooth amorphous layer containing B-site ions of the perovskite oxide was coated first via a controlled hydrolysis and aging process. During hydrothermal treatment and subsequent annealing process, the A-site ions were incorporated in situ into the as-coated amorphous layer preserving the spherical morphology. This synthesis of ferrite/ perovskite oxide core/shell nanostructures was demonstrated in systems like Fe
Magnetic properties of the S = 1/2 antiferromagnet α-Cu2V2O7 have been studied using magnetization, Quantum Monte Carlo (QMC) simulations, and neutron diffraction. Magnetic susceptibility shows a broad peak at ∼ 50 K followed by an abrupt increase indicative of a phase transition to a magnetically ordered state at TN = 33.4(1) K. Above TN , a fit to the Curie-Weiss law gives a Curie-Weiss temperature of Θ = −73(1) K suggesting the dominant antiferromagnetic coupling. The result of the QMC calculations on the helical-honeycomb spin network with two antiferromagnetic exchange interactions J1 and J2 provides a better fit to the susceptibility than the previously proposed spin-chain model. Two sets of the coupling parameters J1 : J2 = 1 : 0.45 with J1 = 5.79(1) meV and 0.65 : 1 with J2 = 6.31(1) meV yield equally good fits down to ∼ TN . Below TN , weak ferromagnetism due to spin canting is observed. The canting is caused by the Dzyaloshinskii-Moriya interaction with an estimated bc-plane component |Dp| 0.14J1. Neutron diffraction reveals that the S = 1/2 Cu 2+ spins antiferromagnetically align in the F d d 2 magnetic space group. The ordered moment of 0.93(9) µB is predominantly along the crystallographic a-axis.
Magnetic skyrmions are attracting interest as efficient information‐storage devices with low energy consumption, and have been experimentally and theoretically investigated in multilayers including ferromagnets, ferrimagnets, and antiferromagnets. The 3D spin texture of skyrmions demonstrated in ferromagnetic multilayers provides a powerful pathway for understanding the stabilization of ferromagnetic skyrmions. However, the manipulation mechanism of skyrmions in antiferromagnets is still lacking. A Hall balance with a ferromagnet/insulating spacer/ferromagnet structure is considered to be a promising candidate to study skyrmions in synthetic antiferromagnets. Here, high‐density Néel‐type skyrmions are experimentally observed at zero field and room temperature by Lorentz transmission electron microscopy in a Hall balance (core structure [Co/Pt]n/NiO/[Co/Pt]n) with interfacial canted magnetizations because of interlayer ferromagnetic/antiferromagnetic coupling between top and bottom [Co/Pt]n multilayers, where the Co layers in [Co/Pt]n are always ferromagnetically coupled. Micromagnetic simulations show that the generation and density of skyrmions are strongly dependent on interlayer exchange coupling (IEC) and easy‐axis orientation. Direct experimental evidence of skyrmions in synthetic antiferromagnets is provided, suggesting that the proposed approach offers a promising alternative mechanism for room‐temperature spintronics.
Although significant advancements in the preparation of metal oxide hollow structures have been achieved, most synthesis routes have some complicated aspects such as requiring a hard-template, multistep procedures or other special reagents. This paper proposes a green and facile bubble-template approach to synthesize and organize Ni-Co hollow microspheres. The entire formation mechanism for the hollow spherical structures, including integration for nucleation, morphological tailoring and an Ostwald ripening process, has been elucidated based on time-dependent observations. The Ni-Co hollow microspheres revealed an excellent cycling stability (730 mA h g(-1) even after 140 cycles at 300 mA g(-1)) and good rate capability when evaluated as an anode material for lithium ion batteries (LIBs). The excellent electrochemical performance can be attributed to the rational design and organization of the hollow structures, which offer a large void space for accommodating volume changes, shorten the diffusion path for Li ions and electron transfer, as well as increase the contact area between the electrodes and electrolyte. Moreover, the synergistic effects of the nickel and cobalt ions with different lithiation potentials allowed the volume change to occur in a stepwise manner. The bubble-template strategy was convenient and very effective for constructing the hollow structures, and if well engineered, it could be extended to the synthesis of other advanced metal oxide anode materials for high energy storage devices and many other applications.
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