This review presents the recent developments in the research hotspots of advanced functional polymers; their concepts, design strategies, and applications are briefly discussed.

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Methyl levulinate (ML) is a biobased platform molecule, which has versatile applications in fine chemical synthesis and food additives. However, during the ML production, one of the main barriers is that humins are usually cogenerated, which leads to poor reaction efficiency and catalyst deactivation. The following findings are herein reported for the first time: in a catalytic system with H-beta25, molecular oxygen could act as both a humins cleaner and a reaction accelerator for the synthesis of value-added ML from 5-hydroxymethylfurfural (HMF) or furfuryl alcohol (FA). The reaction efficiency and the catalyst reusability were significantly improved in the presence of oxygen. Besides, the effects of different reaction parameters as well as catalysts have been investigated. The mechanism of ML formation from HMF in the presence of O 2 and the role of O 2 in humins removal were also proposed.

Nitrogen-containing polymers are a group of fascinating materials, which are usually prepared from nitrogen-containing organic monomers produced from NH3 gas or aqueous solution of ammonia. The direct utilization of safe, clean, convenient, and inexpensive inorganic NH4Cl salt as a nitrogen source for the construction of functional polymers is highly desired but challenging. Multicomponent polymerizations, with their strong designability, structural diversity, high efficiency, simple procedure, and environmental benefit, have been proven to be powerful tools to efficiently convert simple monomers to complex polymer materials. In this work, Cu­(I)-catalyzed multicomponent polymerizations of alkynes, sulfonyl azides, and NH4Cl are developed, utilizing simple inorganic NH4Cl salt to serve as a monomer for the preparation of functional poly­(sulfonyl amidine)­s. The heterogeneous polymerization goes smoothly at room temperature in CH2Cl2/tetrahydrofuran, which is also applicable to a range of different monomer structures, affording seven poly­(sulfonyl amidine)­s with high yields (up to 96%) and high molecular weights (up to 47,100 g/mol). Unique functionalities such as photophysical properties and metal ion detection can be introduced to the poly­(sulfonyl amidine)­s either from monomer structures or the in situ generated product structures, rendering them as selective and sensitive fluorescence sensors for Ru3+. This multicomponent polymerization showed high synthetic efficiency with environmental and economic benefit, which has opened up a feasible synthetic method of using inorganic NH4Cl salt instead of organic amines, isocyanates, isocyanides, or nitriles to construct nitrogen-containing polymers, demonstrating a promising synthetic approach for the synthesis of advanced functional polymer materials.