A new twisted donor–acceptor–donor (D–A–D) multi-photofunctional organic molecule comprising of phenoselenazine as the electron-donors (Ds) and dibenzo[a,j]phenazine (DBPHZ) as the electron-acceptor (A) has been developed. The developed selenium-incorporated D–A–D compound...
Two types of redox functionality were selected for covalent immobilization on a carbon electrode, using an electric potential as the sole stimulus. A redox-active copper catalyst transformed a terminal alkyne in two ways with and without an oxidation process, to form a triazole or butadiyne.
A new class of diamino-substituted π-extended phenazine compound was synthesized, and its photophysical properties were investigated. The U-shaped diaminophenazine displayed photoluminescence in solution with moderate quantum yield. The diamino aromatic compound was found applicable to the poly-condensation with formaldehyde to form Tröger's base ladder polymer. The obtained microporous ladder polymer features high CO 2 adsorption selectivity against N 2 , most likely due to the presence of basic nitrogen atoms in the phenazine rings.
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