Producing indispensable hydrogen and oxygen for social development via water electrolysis shows more prospects than other technologies. Although electrocatalysts have been explored for centuries, a universal activity descriptor for both hydrogen‐evolving (HER) and oxygen‐evolving reactions (OER) has not been developed. Moreover, a unifying concept has not been established to simultaneously understand HER/OER mechanisms. Here, we rationally bridge the relationships between HER/OER activities in three common electrolytes and over 10 representative material properties on 12 3d‐metal‐based model oxides through statistical methodologies. Orbital charge‐transfer energy (Δ) can serve as an ideal universal descriptor, where a neither too large nor too small Δ (∼1 eV) with optimal electron‐cloud density around Fermi level affords the best activities, fulfilling Sabatier's principle. Systematic experiments and computations unravel that pristine oxide with Δ ≈ 1 eV possesses metal‐like high‐valence configurations and active lattice‐oxygen sites to help adsorb key protons in HER and induce lattice‐oxygen participation in OER, respectively. After reactions, partially generated metals in HER and high‐valence hydroxides in OER dominate proton adsorption and couple with pristine lattice‐oxygen activation, respectively. These can be successfully rationalized by the unifying orbital charge‐transfer theory. This work provides the foundation of rational material design and mechanism understanding for many potential applications.This article is protected by copyright. All rights reserved
Corner-sharing and edge-sharing networks are the two most important material genomes. Inspired by the efficient electron transport capacity of corner-sharing structures and the low steric hindrance of edge-sharing units, an attempt is made to exert both merits by combining these two networks. Here, a unique self-assembled hybrid SrCo 0.55 Fe 0.5 O 3-δ nanorod composed of a corner-sharing SrCo 0.5 Fe 0.5 O 3-δ phase and edge-sharing Co 3 O 4 structure is synthesized through a Co-site enrichment method, which exhibits the low overpotentials of 310 and 290 mV at 10 mA cm -2 for oxygen-evolving reaction in 0.1 m and 1.0 m KOH, respectively. This efficiency is attributed to the high Co valence with strong CoO covalence and the short distance between CoCo/Fe metal active sites in hybrid nanorods, realizing a synergistic benefit. Combined multiple operando/ex situ characterizations and computational studies show that the edge-sharing units in hybrid nanorods can help facilitate the deprotonation step of lattice oxygen mechanism (LOM) while the corner-sharing motifs can accelerate the electron transport during LOM processes, triggering an unusual lattice-oxygen activation. This methodology of combining important material structural genomes can offer meaningful insights and guidance for various catalytic applications.
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