Catalytic pyrolysis of waste plastics using low cost binder-free pelletized bentonite clay has been investigated to yield pyrolysis oils as drop-in replacements for commercial liquid fuels such as diesel and gasohol 91.
Activated carbons were prepared from Dipterocarpus alatus fruit by chemical and physical activation and used for the removal of methylene blue from aqueous solution.
The incorporation of oxygen functional groups onto the surface of eucalyptus activated carbon and its surface chemistry were investigated as a function of oxidation conditions, carbon porous properties and carbon preparation method. Under all treatment conditions of increasing time, temperature and oxidant concentration, liquid oxidation with HNO 3 , H 2 O 2 and (NH 4 ) 2 S 2 O 8 and air oxidation led to the increase of acidic group concentration, with carboxylic acid showing the largest percentage increase and air oxidation at the maximum allowable temperature of 350 o C produced the maximum content of both carboxylic acid and total acidic group. Nitric acid oxidation of chemically activated carbon produced higher total acidic content but a lower amount of carboxylic acid compared to the oxidized carbon from physical activation. The increased contents of acidic groups on oxidized carbons greatly enhanced the adsorption capacity of water vapor and heavy metal ions.
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