A non-linear relationship between the conformational change of an n-propyl moiety and photochromic reaction was observed by performing time-dependent X-ray diffraction experiments.
Crystalline-state photochromism of a new organorhodium dinuclear complex having n-methoxypropyltetramethylcyclopentadienyl (η-C5Me4n-C3H6OCH3) and photoresponsive dithionite (μ-O2SSO2) ligands was investigated directly by performing single crystal X-ray diffraction experiments; reversible conformational change of...
Crystalline-state photoreaction of a newly prepared organorhodium dithionite complex with n-hexyltetramethylcyclopentadienyl (CpHex: η5-C5Me4n-Hexyl) ligands was studied by single crystal X-ray diffraction experiments; 2π/5 rotation of the CpHex ligand is induce...
A rhodium dinuclear complex having n-methoxypropyltetramethylcyclopentadienyl (CpMPro = η5-C5Me4n-C3H6OCH3) and photoresponsive dithionite (μ-O2SSO2) ligands, [(CpMProRh)2(μ-CH2)2(μ-O2SSO2] (1MPro), was found to form two polymorphic crystals (a previously reported brock-like α-crystal and a...
A newly synthesized photochromic rhodium dithionite complex with n-methoxybutyl moieties has been found to provide rod-like millimeter-size crystals exhibiting photoinduced bending; the crystals show an intriguing behavior which the bending and unbending occur upon photoirradiation from the same side of the crystal. The bending mechanism was clarified by single crystal X-ray diffraction experiments.
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