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Polystyrene (PS) and poly(methyl methacrylate) (PMMA) blends filled with octadecylamine-functionalized graphene (GE-ODA) have been fabricated to obtain conductive composites with a lower electrical percolation threshold according to the concept of double percolation. The dependence of the electrical properties of the composites on the morphology is examined by changing the proportion of PS and PMMA. Our results reveal that the electrical conductivity of the composites can be optimal when PS and PMMA phases form a cocontinuous structure and GE-ODA nanosheets are selectively located and percolated in the PS phase. For the PS/PMMA blend (50w/50w), the composites exhibit an extremely low electrical percolation threshold (0.5 wt %) because of the formation of a perfect double percolated structure. Moreover, the rheological properties of the composites are also measured to gain a fundamental understanding of the relationship between microstructure and electrical properties.

This review paper summarizes the categories, sensing mechanisms, and affecting factors of flexible conductive polymer composite-based stretchable strain sensors.

Inspired by the human skin, electronic skins (e-skins) composed of various flexible sensors, such as strain sensor, pressure sensor, shear force sensor, temperature sensor, and humility sensor, and delicate circuits, are emerged to mimic the sensing functions of human skins. In this review, the strategies to realize the versatile functionalities of natural skin-like e-skins, including strain-, pressure-, shear force-, temperature-and humility-sensing abilities, as well as self-healing ability and other functions are summarized. Some representative examples of high-performance e-skins and their applications are outlined and discussed. Finally, the outlook of the future of e-skins is presented.

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When the self-assembly of block copolymers (BCPs) occurs within a deformable emulsion droplet, BCPs can aggregate into a variety of nanoscaled particles with unique nanostructures and properties since the confinement effect can effectively break the symmetry of a structure.

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Precise control over the spatial arrangement of inorganic nanoparticles on a large scale is desirable for the design of functional nanomaterials, sensing, and optical/electronic devices. Although great progress has been recently made in controlling the organization of nanoparticles, there still remains a grand challenge to arrange nanoparticles into highly-ordered arrays over multiple length scales. Here, we report the directed arrangement of inorganic nanoparticles into arrayed structures with long-range order, up to tens of microns, by using hexagonally-packed cylindrical patterns of block copolymer nanosheets self-assembled within collapsed emulsion droplets as scaffolds. This technique can be used to generate nanoparticle arrays with various nanoparticle arrangements, including hexagonal honeycomb structures, periodic nanoring structures, and their combinations. This finding provides an effective route to fabricate diverse nanoparticle arrayed structures for the design of functional materials and devices.