The addition of the valley degree of freedom to a two-dimensional spin-polarized electronic system provides the opportunity to multiply the functionality of next-generation devices. So far, however, such devices have not been realized due to the difficulty to polarize the valleys, which is an indispensable step to activate this degree of freedom. Here we show the formation of 100% spin-polarized valleys by a simple and easy way using the Rashba effect on a system with C 3 symmetry. This polarization, which is much higher than those in ordinary Rashba systems, results in the valleys acting as filters that can suppress the backscattering of spin-charge. The present system is formed on a silicon substrate, and therefore opens a new avenue towards the realization of silicon spintronic devices with high efficiency.
An anthracene cyclic hexamer was synthesized by the coupling reaction as a macrocyclic hydrocarbon host. This disk-shaped host included a C guest in 1:1 ratio to form a Saturn-type supramolecular complex in solution and in crystals. X-ray analysis unambiguously revealed that the guest molecule was accommodated in the middle of the host cavity with several CH⋅⋅⋅π contacts. The association constant K determined by NMR titration measurements was 2.3×10 L mol at 298 K in toluene. The structural features and the role of CH⋅⋅⋅π interactions are discussed with the aid of DFT calculations.
Reactive oxygen species (ROS) produced by NADPH oxidases, called respiratory burst oxidase homologs (Rbohs), play crucial roles in development as well as biotic and abiotic stress responses in plants. Arabidopsis has 10 Rboh genes, AtRbohA to AtRbohJ. Five AtRbohs (AtRbohC, -D, -F, -H and -J) are synergistically activated by Ca 2+ -binding and protein phosphorylation to produce ROS that play various roles in planta, although the activities of the other Rbohs remain unknown. With a heterologous expression system, we found a range of ROS-producing activity among the AtRbohs with differences up to 100 times, indicating that the required amounts of ROS are different in each situation where AtRbohs act. To specify the functions of AtRbohs involved in cell growth, we focused on AtRbohC, -H and -J, which are involved in tip growth of root hairs or pollen tubes. Ectopic expression of the root hair factor AtRbohC/ROOT HAIR DEFEC-TIVE 2 (RHD2) in pollen tubes restored the atrbohH atrbohJ defects in tip growth of pollen tubes. However, expression of AtRbohH or -J in root hairs did not complement the tip growth defect in the atrbohC/rhd2 mutant. Our data indicate that Rbohs possess different ranges of enzymatic activity, and that some Rbohs have evolved to carry specific functions in cell growth.
This article proposes new methods for enhancing the active harvest of piezoelectric energy using the synchronized switch harvesting on inductor (SSHI) technique. It was experimentally confirmed that the energy harvested by the original synchronized switch harvesting on inductor technique was decreased by the suppression of the vibration amplitude, and this critical problem was solved by developing new control strategies, namely, switch harvesting considering vibration suppression (SCVS) and adaptive SCVS (ASCVS). The SCVS technique was designed to intentionally skip some of the switching actions of the original synchronized switch harvesting on inductor technique, while the ASCVS technique enables more flexible variation of the number of skipped switching actions. The skipping of the switching actions facilitates the recovery of the vibration amplitude produced by the excitation force, and the developed strategies thus maintain the vibration amplitude at the highest possible level, resulting in increased energy harvest. The results of the experimental implementation of the proposed strategies showed that they enabled the harvesting of as much as 10.5 times the energy harvested by the original synchronized switch harvesting on inductor technique. The ASCVS technique particularly enables flexible enhancement of the harvested energy under various vibration conditions.
This paper proposes an innovative energy-harvesting controller to increase energy harvested from vibrations. Energy harvesting is a process that removes mechanical energy from a vibrating structure, which necessarily results in damping. The damping associated with piezoelectric energy harvesting suppresses the amplitude of mechanical vibration and reduces the harvested energy. To address this critical problem, we devise an energy-harvesting controller that maintains the vibration amplitude as high as possible to increase the harvested energy. Our proposed switching controller is designed to intentionally stop the switching action intermittently. We experimentally demonstrate that the proposed control scheme successfully increases the harvested energy. The piezoelectric voltage with the proposed controller is larger than that with the original synchronized switching harvesting on inductor (SSHI) technique, which increases the harvested energy. The stored energy with our controller is up to 5.7 times greater than that with the conventional SSHI control scheme.
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