Precipitation and recrystallization behavior during the continuous heat treatment of three beta-titanium alloys with various molydenum equivalents (VT22, Ti-15-3, and TIMETAL-LCB) was established. Following solution treatment, the materials were cold deformed to various reductions and then heated at rates between 0.17 and 50 K s Ϫ1 to peak temperatures below and above the beta-transus temperature. Precipitation below the transus was most rapid for the alloy with the least amount of beta stabilizing elements (VT22) and next fastest for the most-highly-alloyed material (TIMETAL-LCB), an effect ascribed to its large iron content. The reduction level was found to have a very strong influence on the uniformity of recrystallization and the recrystallized grain size. Because of the competition between precipitation and the temperature dependence of recrystallization nucleation and growth, the heatingrate dependence of the recrystallization temperature for the beta-titanium alloys was weak.
Abstract. It was shown very recently that despite high thermal stability some high entropy alloys, namely, intermetallic compounds of TiZrHfCoNiCu family, undergo martensitic transformation and exhibit shape memory effect [1]. It was also found that X-ray diffraction patterns taken from those compounds resemble qualitatively ones of B2 ordering type for austenitic state and B19` -for martensite. It is going to be shown [2] that the ordered structure of austenite phase is not B2 but is a result of group-subgroup transition down to triclinic P1 space group. Present paper reports onto the results of electron structure modelling combined with crystal structure analysis with the help of experimental data Rietveld refinement performed for TiZrHfCoNiCu intermetallics. Crystal structures of austenite and martensite phases for these high entropy intermetallics will be discussed.
The atomic structure and mechanical properties of the carbyne (monatomic
linear chains), containing from 2 to 21 carbon atoms, are theoretically
investigated by ab-initio methods. We demonstrate the existence of a stable
cumulene-structure in the inner part of chains with the number of atoms N>=10.
We present a general stress-strain diagram of chains until the moment when they
break, which enables to determine their strength, elasticity and fragility. For
chains with N>=4, the relationship between the strength of the chain and the
binding energy of the edge atom in the chain is established. The existence of
scale-effect and "even-odd" effect for such properties as strength, elasticity
and fragility is observed. We demonstrate that the 5-atom carbon chains show
the maximum strength value.Comment: 8 pages, figure
The results of the high-field technique for obtaining and testing the carbyne strength in situ are presented. By using molecular dynamics simulation and ab initio calculations, a comprehensive analysis of the results is executed. High-field technique for experimental measurement of the carbyne strength in situ is briefly described. It is shown that the technique used gives a lower estimation for strength of carbyne, which equals 251 GPa at T = 77 K. This value is close to the strength 7.85 nN (250 GPa) of contact atomic bond between carbyne and graphene sheet, from which the monatomic chain is pulled. The strength of carbyne itself is determined by strength of an edge atomic bond and it is ≈ 12.35 nN (393 GPa) at T = 0 K. For carbynes containing more than 10 to 12 atoms, the coefficient of elasticity (kY = 145.40 nN) and the elastic modulus (Y = 4631 GPa) are ascertain.
An approach is developed to predict stability of carbyne-based nanodevices. Within this approach, the thermo-fluctuation model of instability and break of contact bond in nanodevices, containing carbyne chains and graphene sheets, is offered. Unlike the conventional models, it does not include empirical constants. The results of DFT calculations are used as initial data for this model. Possibility of synergistic effect of temperature and mechanical load on stability and value of service time of carbyne-based nanodevices is predicted. It is ascertained, that this synergism results in a significant (by many orders of magnitude) decrease in the lifetime of nanodevices containing carbyne chains. The atomic mechanism of this phenomenon is outlined. Conditions of thermo-force loading are predicted at which a service time of these devices is sufficient for applications.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.