The release of antibiotics into the water environment can pose a serious threat to human and ecological health, so it is of great significance to effectively remove antibiotics from wastewater. In this work, porphyrinic zirconium metal−organic framework material, PCN-224, was first explored for the adsorption removal of antibiotics from water using tetracycline (TC) and ciprofloxacin (CIP) as examples. We prepared a series of PCN-224 with different particle sizes (150 nm, 300 nm, 500 nm, and 6 μm). Benefiting from the huge surface area (1616 m 2 g −1 ), the 300 nm-PCN-224 sample had the best adsorption properties for TC and CIP. Remarkably, it exhibits fast removal rates and high adsorption capacities of 354.81 and 207.16 mg g −1 for TC and CIP, respectively. The adsorption of TC and CIP in 300 nm-PCN-224 is consistent with the pseudo-second-order kinetic model and Langmuir isotherm model, which indicates that the adsorption can be regarded as homogeneous monolayer chemisorption, and the adsorption is exothermic, which has been confirmed by thermodynamic studies. Under visible-light irradiation, 300 nm-PCN-224 exhibited high photocatalytic activity for TC and CIP. The adsorption studies confirmed that the adsorption of adsorbates takes place via the formation of hydrogen bonding, π−π interactions, and electrostatic attraction. In addition, the adsorbent can be simply regenerated by photocatalysis under visible light, and the adsorption−desorption efficiency is still above 85% after repeated use five times. The work of MOFs to remove antibiotics from water shows that MOFs have great potential in this field and are worthy of further study.

Visible-lightdriven C–TiO2 nanocomposites were prepared via a simple calcination and acid etching process. The C–TiO2 nanocomposites were characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, and high-resolution TEM. The results showed that TiO2 nanoparticles were combined with a porous carbon layer through surface C–O groups, which facilitates the strong interface interaction. The interface combination of nano-TiO2 and carbon material increases the specific surface area of nano-TiO2, widens the range of light response, and improves the efficiency of light-induced electron migration. The visible-light photocatalytic activity of the prepared photocatalyst was evaluated by the decomposition of tetracycline aqueous solution. Compared with that of pure TiO2, the photocatalytic activity of C–TiO2 nanocomposites was significantly improved. Furthermore, a possible photocatalytic mechanism was also tentatively proposed. This work can promote the development of active photocatalysts under solar light for the photodegradation of environmental pollutants.

Oxygen vacancies (OVs) defect in metal oxide-based photocatalysts play crucial role in improving their charge carrier separation efficiencies to enhance their photocatalytic performances. In this work, OVs were introduced in...

Fe (III)-grafted Bi 2 MoO 6 nanoplates (Fe (III)/BMO) with varying small quantity of Fe (III) clusters modification were fabricated through a simple hydrothermal and impregnation process. The characterization results indicate that the modification of Fe (III) clusters on the surface of Bi 2 MoO 6 nanoplates with intimate interfacial contact is beneficial to the expansion of visible light absorption range and the separation of photoinduced carriers during the interface charge transfer process. The photocatalytic properties of the samples were studied by degradation of tetracycline (TC) and selective aerobic oxidation of biomass-derived chemical 5-hydroxymethylfuraldehyde (HMF) under visible light. The 1.5 wt% Fe (III) clusters-grafted Bi 2 MoO 6 nanoplates exhibited optimum photocatalytic activity, which is the TC degradation kinetic rate constant is 5.3 times higher than that of bare BMO, and the highest HMF conversion of 32.62% can be obtained with a selectivity of 95.30%. Furthermore, a possible visible light photocatalysis mechanism over Fe (III)/BMO sample has been proposed. This study may supply some insight for the development of visiblelight-driven Bi 2 MoO 6 -based photocatalysts applicable to both environmental remediation and biomass-derived chemical transformation.

A ternary photocatalyst, Fe3O4-loaded g-C3N4/C-layered composite (g-C3N4/C/Fe3O4) was fabricated by a facile sonication and in situ precipitation technique. Carbon nanosheets were prepared using the remaining non-metallic components of waste printed circuit boards as carbon sources. In this hybrid structure, g-C3N4 was immobilized on the surfaces of carbon nanosheets to form a layered composite, and 10–15 nm Fe3O4 nanoparticles are uniformly deposited on the surface of the composite material. The photocatalytic performance of the catalyst was studied by degrading tetracycline (TC) under simulated sunlight. The results showed that the photoactivity of the g-C3N4/C/Fe3O4 composite to TC was significantly enhanced, and the degradation rate was 10.07 times higher than that of pure g-C3N4, which was attributed to Fe3O4 nanoparticles and carbon nanosheets. Carbon sheets with good conductivity are an excellent electron transporter, which promotes the separation of photogenerated carriers and the Fe3O4 nanoparticles can utilize electrons effectively as a center of oxidation–reduction. Moreover, a possible photocatalytic mechanism for the excellent photocatalytic performance was proposed.

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This study investigates the degradation of dimethyl phthalate (DMP) with hydrogen peroxide and ferrate (Fe(VI)) under various reaction conditions. The results showed that the optimum conditions for dimethyl phthalate removal from water were as follows: (a) pH 7.0 and (b) the original molar ratio of [Fe(VI)]/[H 2 O 2 ]/[DMP] equal to 10:2:1. Under the optimum conditions, the degradation rate of DMP can reach 89.7% in 360 min. Furthermore, 2,5-dihydroxybenzaldehyde, isophthalic acid, 2-ethylhexanol, oxalic acid, 2,6-dihydroxybenzoic acid, 2,6-dihydroxybenzaldehyde, 2,5-dihydroxybenzoic acid, and monomethyl phthalate were identified as the degradation intermediates, and degradation pathways were proposed.