Ternary blend approaches are demonstrated as a universal means to improve overall performance of organic photovoltaics (OPVs) in both indoor and outdoor conditions. A comparative study on two donors:one acceptor (2D:1A) and one donor:two acceptors (1D:2A) ternary blends shows that both approaches are universally effective for indoor and outdoor operation; the 1D:2A devices incorporating a nonfullerene acceptor (NFA) benefit from less charge recombination and higher power conversion efficiencies (PCEs) for various irradiation conditions, while the performance of the 2D:1A blends depends on the emission spectrum of the incident light source. The synergistic merits of NFAs and ternary structure in the 1D:2A ternary OPVs secure better performance and generality regardless of the incident lighting. A combination of experimental and theoretical analyses unveils that NFAs optimize packing and arrangement of molecules to build efficient cascade ternary junctions in the 1D:2A blends, which can be important design guidelines for the third component in ternary OPVs. The optimized 1D:2A ternary OPV exhibits a new record PCE of 25.6% under a 200 lux light‐emitting diode (LED) and 26.4% under a 1000 lux LED, and superior durability under industrial relevant thermal stress, suggesting new opportunities in diverse practical applications challenging the currently dominant PV technologies.
In two-dimensional (2D) borophene, the structural transition from triangular lattice to hexagonal lattice with an increase in vacancy concentration is a basic principle of constructing various borophene isomers. Here, by performing an extensive structural search of 4239 borophene isomers with both hexagonal holes (HHs) and large holes (LHs), we show that the structural transformation from triangular lattice to borophene with large holes is energetically more favorable. Borophene isomers with LHs are more stable than those with only HHs at high vacancy concentrations (>20%) and are just slightly less stable than those with only HHs at low vacancy concentrations. This discovery greatly expands the family of 2D borophene and opens a route for synthesizing new borophene isomers.
We demonstrate the improved morphological stability and lifetime of ternary organic solar cells incorporating nonfullerene small molecules in polymer:fullerene blends.
Objective: We examined the localization and expression of H<sup>+ pumping vacuolar ATPase (V-ATPase) and cytokeratin 5 (KRT5) in the epididymis of pigs, expressed in clear and basal cells, respectively, during postnatal development.Methods: Epididymides were obtained from pigs at 1, 7, 21, 60, 120, and 180 days of age; we observed the localization and expression patterns of V-ATPase and KRT5 in the different regions of these organs, namely, the caput, corpus, and cauda. The differentiation of epididymal epithelial cells was determined by immunofluorescence labeling using cell-type-specific markers and observed using confocal microscopy.Results: At postnatal day 5 (PND5), the localization of clear cells commenced migration from the cauda toward the caput. Although at PND120, goblet-shaped clear cells were detected along the entire length of the epididymis, those labeled for V-ATPase had disappeared from the corpus to cauda and were maintained only in the caput epididymis in adult pigs. In contrast, whereas basal cells labeled for KRT5 were only present in the vas deferens at birth, they were detected in all regions of the epididymis at PND60. These cells were localized at the base of the epithelium; however, no basal cells characterized by luminally extending cell projections were observed in any of the adult epididymides examined.Conclusion: The differentiation of clear and basal cells progressively initiates in a retrograde manner from the cauda to the caput epididymis. The cell-type-specific distribution and localization of the epithelial cells play important roles in establishing a unique luminal environment for sperm maturation and storage in the pig epididymis.
Rationale Molecular dynamics (MD) simulations with finite temperature were performed to improve the theoretical prediction of collisional cross section (CCS) values, especially for aromatic compounds containing long alkyl chains. Methods In this study, the CCS values of 11 aromatic compounds with long alkyl chains were calculated by MD simulations while considering internal energy at 300, 500, and 700 K, and the results were compared with experimentally determined values. Results The CCS values calculated at higher energies showed better agreement with the experimental values. Polycyclic aromatic hydrocarbons (PAHs) such as pentacene and benz[b]anthracene were also investigated, and better agreement between the theoretical and experimental results was observed when higher temperature (or higher internal energy) was considered. Conclusions The data presented in this study show that the internal degrees of freedom of ions must be considered to accurately predict the CCS values of aromatic compounds with a flexible structure measured by ion mobility mass spectrometry.
In this paper, we present the feasibility of an optical color sensing feedback system for an LED backlight by integrating the amorphous silicon color sensor onto the LCD panel. To improve the well-known photoconductivity degradation of amorphous silicon, a new LASER immersion treatment has been applied. The integrated color sensor optical feedback controlled LED backlighting system improved the color variation to less than 0.008 ∆u'v' (CIE1976) compared with 0.025 for an open loop system over the temperature range of 42℃ to 76℃.
A large-scale ion trap array fabricated using the microelectromechanical systems (MEMS) technology is expected to be a promising device for building a practical quantum computer. Shuttling trapped ions is essential for operating scalable ion trap structures. This paper proposes an ion shuttling method for a MEMS-fabricated surface ion trap. Change of secular frequency of trapping potential can cause heating and subsequent loss of ions. Therefore, direct current voltage sets to form uniform ion trapping potentials around the ions while shuttling are calculated by simulations. A 32-channel digital-to-analog converter system is developed to apply the calculated voltage sets to the electrodes of the MEMS-fabricated surface ion trap. The shuttling process is experimented using trapped 174Yb+ ions. The successful round trip of the ion for 1920 μm is demonstrated using the developed approach.
Glucose in the blood is generally measured by electrochemical method using glucose oxidase (GOx) which acts as enzymes and reduced graphene oxide (rGO) composite. The rGO, which has low dispersibility, reduces the sensing capability of sensors. In order to solve this problem, the rGO electrodes with the addition of polyvinylpyrrolidone (PVP) have been reported. However, rGO with low electrical conductivity and mobility is not compatible to the electrochemical system. In this study, graphene with excellent electrical properties was added to PVP protected rGO. The rGO was synthesized using a Hummer and Offeman's method. Graphene was synthesized using chemical vapor deposition (CVD) with a Cu catalyst. Platinum (Pt) electrodes, Ag/AgCl, and PVP protected rGO were used as working electrode, reference electrode, and counter electrode, respectively. Surface morphology and structural properties of graphene were analyzed using atomic force microscopy (AFM), Raman spectroscopy, and Fourier transform infrared spectroscopy (FT-IR). Cyclic voltametry (CV) and I-V probe station were used to analyze the performance of the electrodes. Glucose concentration was systematically varied and the reduction current was monitored using I-V probe station.
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