The glass-forming ability is an important material property for manufacturing glasses and understanding the long-standing glass transition problem. Because of the nonequilibrium nature, it is difficult to develop the theory for it. Here we report that the glass-forming ability of binary mixtures of soft particles is related to the equilibrium melting temperatures. Due to the distinction in particle size or stiffness, the two components in a mixture effectively feel different melting temperatures, leading to a melting temperature gap. By varying the particle size, stiffness, and composition over a wide range of pressures, we establish a comprehensive picture for the glass-forming ability, based on our finding of the direct link between the glassforming ability and the melting temperature gap. Our study reveals and explains the pressure and interaction dependence of the glass-forming ability of model glass-formers, and suggests strategies to optimize the glass-forming ability via the manipulation of particle interactions.

By introducing four fundamental types of disorders into a two-dimensional triangular lattice separately, we determine the role of each type of disorder in the vibration of the resulting massspring networks. We are concerned mainly with the origin of the boson peak and the connection between the boson peak and the transverse Ioffe-Regel limit. For all types of disorders, we observe the emergence of the boson peak and Ioffe-Regel limits. With increasing disorder, the boson peak frequency ωBP , transverse Ioffe-Regel frequency ω . Therefore, the argument that the boson peak is equivalent to the transverse Ioffe-Regel limit is not general. Our results suggest that both local coordination number and positional disorder are necessary for the argument to hold, which is actually the case for most disordered solids such as marginally jammed solids and structural glasses. We further combine two types of disorders to cause disorder in both the local coordination number and lattice site position. The density of vibrational states of the resulting networks resembles that of marginally jammed solids well. However, the relation between the boson peak and the transverse Ioffe-Regel limit is still indefinite and condition-dependent. Therefore, the interplay between different types of disorders is complicated, and more in-depth studies are required to sort it out.

For nonequilibrium systems, how to define temperature is one of the key and difficult issues to solve. Although effective temperatures have been proposed and studied to this end, it still remains elusive what they actually are. Here, we focus on the fluctuation-dissipation temperatures and report that such effective temperatures of slow-evolving systems represent characteristic temperatures of their equilibrium counterparts. By calculating the fluctuation-dissipation relation of inherent structures, we obtain a temperature-like quantity TIS. For monocomponent crystal-formers, TIS agrees well with the crystallization temperature Tc, while it matches with the onset temperature Ton for glass-formers. It also agrees with effective temperatures of typical nonequilibrium systems, such as aging glasses, quasi-static shear flows, and quasi-static self-propelled flows. From the unique perspective of inherent structures, our study reveals the nature of effective temperatures and the underlying connections between nonequilibrium and equilibrium systems and confirms the equivalence between Ton and Tc.

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Glasses feature universally low-frequency excess vibrational modes beyond Debye prediction, which could help rationalize, e.g., the glasses’ unusual temperature dependence of thermal properties compared to crystalline solids. The way the density of states of these low-frequency excess modes D( ω) depends on the frequency ω has been debated for decades. Recent simulation studies of 3D glasses suggest that D( ω) scales universally with ω4 in a low-frequency regime below the first sound mode. However, no simulation study has ever probed as low frequencies as possible to test directly whether this quartic law could work all the way to extremely low frequencies. Here, we calculated D( ω) below the first sound mode in 3D glasses over a wide range of frequencies. We find D( ω) scales with ω β with β < 4 at very low frequencies examined, while the ω4 law works only in a limited intermediate-frequency regime in some glasses. Moreover, our further analysis suggests our observation does not depend on glass models or glass stabilities examined. The ω4 law of D( ω) below the first sound mode is dominant in current simulation studies of 3D glasses, and our direct observation of the breakdown of the quartic law at very low frequencies thus leaves an open but important question that may attract more future numerical and theoretical studies.

In marginally jammed solids confined by walls, we calculate the particle and ensemble averaged value of an order parameter, 〈Ψ(r)〉, as a function of the distance to the wall, r. Being a microscopic indicator of structural disorder and particle mobility in solids, Ψ is by definition the response of the mean square particle displacement to the increase of temperature in the harmonic approximation and can be directly calculated from the normal modes of vibration of the zero-temperature solids. We find that, in confined jammed solids, 〈Ψ(r)〉 curves at different pressures can collapse onto the same master curve following a scaling function, indicating the criticality of the jamming transition. The scaling collapse suggests a diverging length scale and marginal instability at the jamming transition, which should be accessible to sophisticatedly designed experiments. Moreover, 〈Ψ(r)〉 is found to be significantly suppressed when approaching the wall and anisotropic in directions perpendicular and parallel to the wall. This finding can be applied to understand the r-dependence and anisotropy of the structural relaxation in confined supercooled liquids, providing another example of understanding or predicting behaviors of supercooled liquids from the perspective of the zero-temperature amorphous solids.

Recent studies have shown that the melting of two-dimensional crystals can be either continuous or discontinuous, relying on multiple parameters such as particle stiffness, density, and particle size dispersity. However,...