Development
of large-area, low-cost, low-voltage, low-power consumption,
flexible high-performance printed carbon nanotube thin-film transistors
(TFTs) is helpful to promote their future applications in sensors
and biosensors, wearable electronics, and the Internet of things.
In this work, low-voltage, flexible printed carbon nanotube TFTs with
a large-area and low-cost fabrication process were successfully constructed
using ultrathin (∼3.6 nm) AlO
x
thin
films formed by plasma oxidation of aluminum as dielectrics and screen-printed
silver electrodes as contact electrodes. The as-prepared bottom-gate/bottom-contact
carbon nanotube TFTs exhibit a low leakage current (∼10–10 A), a high charge carrier mobility (up to 9.9 cm2 V–1 s–1), high on/off
ratios (higher than 105), and small subthreshold swings
(80–120 mV/dec) at low operation voltages (from −1.5
to 1 V). At the same time, printed carbon nanotube TFTs showed a high
response (ΔR/R = 99.6%) to
NO2 gas even at 16 ppm with a faster response and recovery
speed (∼8 s, exposure to 0.5 ppm NO2), a lower detection
limit (0.069 ppm NO2), and a low power consumption (0.86
μW, exposure to 16 ppm NO2) at a gate voltage of
0.2 V at room temperature. Moreover, the printed carbon nanotube devices
exhibited excellent mechanical flexibility and bias stress stability
after 12,000 bending cycles at a radius of 5 mm and a bias stress
test for 7200 s at a gate voltage of ±1 V, which originated from
the ultrathin and compact AlO
x
dielectric
and the super adhesion force between screen-printed silver electrodes
and polyethylene terephthalate substrates.
We construct flexible fully-printed all-carbon thin film transistors, which show excellent electrical properties, mechanical flexibility and high sensitivity (346.73%) to NH3 with good selectivity, low limit of detection and low power consumption.
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