Thermodynamic stability of statistical systems requires that susceptibilities be semipositive and finite. Susceptibilities are known to be related to the fluctuations of extensive observable quantities. This relation becomes nontrivial, when the operator of an observable quantity is represented as a sum of operators corresponding to the extensive system parts. The association of the dispersions of the partial operator terms with the total dispersion is analyzed. Special attention is paid to the dependence of dispersions on the total number of particles in the thermodynamic limit. An operator dispersion is called thermodynamically normal if it is proportional to at large values of the latter. While, if the dispersion is proportional to a higher power of , it is termed thermodynamically anomalous. The following theorem is proved: The global dispersion of a composite operator, which is a sum of linearly independent self-adjoint terms, is thermodynamically anomalous if and only if at least one of the partial dispersions is anomalous, the power of in the global dispersion being defined by the largest partial dispersion. Conversely, the global dispersion is thermodynamically normal if and only if all partial dispersions are normal. The application of the theorem is illustrated by several examples of statistical systems. The notion of representative ensembles is formulated. The relation between the stability and equivalence of statistical ensembles is discussed.
The stability of solutions to evolution equations with respect to small stochastic perturbations is considered. The stability of a stochastic dynamical system is characterized by the local stability index. The limit of this index with respect to infinite time describes the asymptotic stability of a stochastic dynamical system. Another limit of the stability index is given by the vanishing intensity of stochastic perturbations. A dynamical system is stochastically unstable when these two limits do not commute with each other. Several examples illustrate the thesis that there always exist such stochastic perturbations which render a given dynamical system stochastically unstable. The stochastic instability of quasi-isolated systems is responsible for the irreversibility of time arrow.02.50.Ey, 02.30.Jr, 05.70.Ln
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.