Electric-field-driven oxygen ion evolution in the metal/oxide heterostructures emerges as an effective approach to achieve the electric-field control of ferromagnetism. However, the involved redox reaction of the metal layer typically requires extended operation time and elevated temperature condition, which greatly hinders its practical applications. Here, we achieve reversible sub-millisecond and room-temperature electric-field control of ferromagnetism in the Co layer of a Co/SrCoO2.5 system accompanied by bipolar resistance switching. In contrast to the previously reported redox reaction scenario, the oxygen ion evolution occurs only within the SrCoO2.5 layer, which serves as an oxygen ion gating layer, leading to modulation of the interfacial oxygen stoichiometry and magnetic state. This work identifies a simple and effective pathway to realize the electric-field control of ferromagnetism at room temperature, and may lead to applications that take advantage of both the resistance switching and magnetoelectric coupling.
3D porous Cu foil fabricated by the painting–alloying–dealloying method exhibits excellent electrochemical performance as a current collector for Li metal batteries.
Rice sheath blight, caused by Rhizoctonia solani is one of the major diseases of rice. The pathogen infects rice plants directly through stomata or using lobate appressoria and hyphal masses called infection cushions. The infection structures were normally found at 36 h post-inoculation. During infection, the pathogenesis-related genes, PR1b and PBZ1 were induced in rice plants. To identify rice genes induced early in the defense response, suppression subtractive hybridization (SSH) was used to generate a cDNA library enriched for transcripts differentially expressed during infection by R. solani. After differential screening by membrane-based hybridization and subsequent confirmation by reverse Northern blot analysis, selected clones were sequenced. Fifty unique cDNA clones were found and assigned to five different functional categories. Most of the genes were not previously identified as being induced in response to pathogens. We examined expression of 100 rice genes induced by infection with Magnaporthe grisea, Xanthomonas oryzae pv. oryze (Xoo) and X. oryzae pv. oryzicola (Xooc). Twenty-five of them were found to be differentially expressed after the sheath blight infection, suggesting overlap of defense responses to different fungal and bacterial pathogens infection.
Antimony (Sb) has captured extensive attention as a promising anode for sodium-ion batteries (SIBs) due to its high theoretical capacity and moderate sodiated potential but is held back from practical applications owing to its pulverization induced by dramatic volumetric variations during the (de)sodiation process. Herein, we report a core−shell Sb@Co(OH) 2 nanosheet anode fabricated via magnetron sputtering Sb onto the mass-productive Co(OH) 2 substrate anchored on stainless-steel mesh, which is scalable and suitable for flow-line production. In SIBs, the Sb@Co(OH) 2 anode displays superior rate performance (383.5 mAh/g at 30 A/g), high discharge capacity, and excellent stability. Compared with the sputtered Sb film electrode, the improved performance of the core−shell Sb@Co(OH) 2 nanosheet anode can be attributed to the open framework of the Co(OH) 2 substrate, not only accelerating the ion and electron transfer but also serving as the buffer for alleviating the volumetric variation and the supporting scaffold for prohibiting the aggregation. More importantly, the (de)sodiation mechanism of the Sb@Co(OH) 2 anode was explored by operando (in situ) X-ray diffraction, and the similar alloying−dealloying processes (Sb ↔ Na x Sb ↔ Na 3 Sb) for the 1st, 13th, and 30th cycles illustrate the excellent stability of the electrode.
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