Temporal change in urbanization‐induced warming at two national basic meteorological stations of China and its contribution to the overall warming are analyzed. Annual and seasonal mean surface air temperature for time periods of 1961∼2000 and 1981∼2000 at the two stations of Beijing and Wuhan Cities and their nearby rural stations all significantly increase. Annual and seasonal urbanization‐induced warming for the two periods at Beijing and Wuhan stations is also generally significant, with the annual urban warming accounting for about 65∼80% of the overall warming in 1961∼2000 and about 40∼61% of the overall warming in 1981∼2000. This result along with the previous researches indicates a need to pay more attention to the urbanization‐induced bias probably existing in the current surface air temperature records of the national basic stations.
Monotonous luminescence has always been a major factor limiting the application of organic room‐temperature phosphorescence (RTP) materials. Enhancing and regulating the intermolecular interactions between the host and guest is an effective strategy to achieve excellent phosphorescence performance. In this study, intermolecular halogen bonding (CN⋅⋅⋅Br) was introduced into the host–guest RTP system. The interaction promoted intersystem crossing and stabilized the triplet excitons, thus helping to achieve strong phosphorescence emission. In addition, the weak intermolecular interaction of halogen bonding is sensitive to external stimuli such as heat, mechanical force, and X‐rays. Therefore, the triplet excitons were easily quenched and colorimetric multi‐stimuli responsive behaviors were realized, which greatly enriched the luminescence functionality of the RTP materials. This method provides a new platform for the future design of responsive RTP materials based on weak intermolecular interactions between the host and guest molecules.
Trends in surface air temperature (SAT) are a critical indicator for climate change at varied spatial scales. Because of urbanization effects, however, the current SAT records of many urban stations can hardly meet the demands of the studies. Evaluation and adjustment of the urbanization effects on the SAT trends are needed, which requires an objective selection of reference (rural) stations. Based on the station history information from all meteorological stations with long-term records in mainland China, an integrated procedure for determining the reference SAT stations has been developed and is applied in forming a network of reference SAT stations. Historical data from the network are used to assess the urbanization effects on the long-term SAT trends of the stations of the national Reference Climate Network and Basic Meteorological Network (RCN1BMN or national stations), which had been used most frequently in studies of regional climate change throughout the country. This paper describes in detail the integrated procedure and the assessment results of urbanization effects on the SAT trends of the national stations applying the data from the reference station network determined using the procedure. The results showed a highly significant urbanization effect of 0.0748C (10 yr) 21 and urbanization contribution of 24.9% for the national stations of mainland China during the time period 1961-2004, which compared well to results that were reported in previous studies by the authors using the predecessor of the present reference network and the reference stations selected but when applying other methods. The authors are thus confident that the SAT data from the updated China reference station network as reported in this paper best represented the baseline SAT trends nationwide and could be used for evaluating and adjusting the urban biases in the historical data series of the SAT from different observational networks.
Land use/cover change induced by human activities has emerged as a "global" phenomenon with Earth system consequences. Northeast China is an area where the largest land cultivation activities by migrants have happened in China during the past 300 years. In this paper, methods including documentary data calibration and multi-sourced data conversion model are used to reconstruct historical cropland cover change in Northeast China during the past 300 years. It is concluded that human beings have remarkably changed the natural landscape of the region by land cultivation in the past 300 years. Cropland area has increased almost exponentially during the past 300 years, especially during the past 100 years when the ratio of cropland cover changed from 10% to 20%. Until the middle of the 19th century, the agricultural area was still mainly restricted in Liaoning Province. From the late 19th century to the early 20th century, dramatic changes took place when the northern boundary of cultivation had extended to the middle of Heilongjiang Province. During the 20th century, three agricultural regions with high ratio of cropland cover were formed after the two phases of spatial expansion of cropland area in 1900s-1930s and 1950s-1980s. Since 1930s-1940s, the expansion of new cultivated area have invaded the forest lands especially in Jilin and Heilongjiang Provinces.past 300 years, Northeast China, cropland, land cover, environmental change
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